Answer:
attached below
Explanation:
Structure of two acyclic compounds with 3 or more carbons that exhibits one singlet in 1H-NMR spectrum
a) Acetone CH₃COCH₃
Attached below is the structure
b) But-2-yne (CH₃C)₂
Attached below is the structure
Half life is the time that it takes for half of the original value of some amount of a radioactive element to decay.
We have the following equation representing the half-life decay:

A is the resulting amount after t time
Ao is the initial amount = 50 mg
t= Elapsed time
t half is the half-life of the substance = 14.3 days
We replace the know values into the equation to have an exponential decay function for a 50mg sample

That would be the answer for a)
To know the P-32 remaining after 84 days we have to replace this value in the equation:

So, after 84 days the P-32 remaining will be 0.85 mg
Use the universal gas formula
PV=nRT
where
P=pressure ( 0.980 atm)
V=volume (L)
T=temperature ( 23 ° C = 23+273.15 = 296.15 ° K)
n=number of moles of ideal gas (0.485 mol)
R=universal gas constant = <span>0.08205 L atm / (mol·K)
Substitute values,
Volume, V (in litres)
=nRT/P
=0.485*0.08205*296.15/0.980
= 12.0256 L
= 12.0 L (to three significant figures)
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mol=35:101.11 g/mol=0.346
formula units = 0.346 x 6.02 x 10²³ = 2.082 x 10²³