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DanielleElmas [232]
3 years ago
7

What is the pH of a solution of 0.600 M K2HPO4, potassium hydrogen phosphate?

Chemistry
2 answers:
AleksAgata [21]3 years ago
5 0
<span>When pKas of polyprotic intermediates have a difference of 2 or more you just average them using the equation: pH = (pKa2 + pKa3) / 2  </span>
<span>pKa2 = -log(Ka2) ; pKa3 = -log(Ka3) </span>
<span>so, for this problem, REGARDLESS OF THE CONCENTRATION GIVEN, the answer is:  </span>
<span>pH = (7.2076+12.3767) / 2  </span>
<span>pH = 9.79</span>
liraira [26]3 years ago
4 0

Answer:

9.8

Explanation:

The salt K₂HPO₄ will dissociate to form the ions K⁺ and HPO₄⁻², and because of the stoichiometry of the dissociation (1:2:1) [HPO₄⁻²] = 0.600 M. So, two reactions may happen:

HPO₄⁻² + H₂O ⇄ H₂PO₄⁻ + OH⁻

HPO₄⁻² + H₂O ⇄ PO₄⁻³ + OH⁻

H₃PO₄ is a polyprotic acid and have the values of pKa:

pKa1 = 2.15

pKa2 = 7.21

pKa3 = 12.4

In this case, the second and the third equilibrium are presented, thus, the pH depends only on the pKa values, and it will be:

pH = (1/2)*(pKa2 + pKa3)

pH = (1/2)*(7.21 + 12.4)

pH = 9.8

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Answer:

5Fe⁺² + MnO₄⁻ + 8H⁺ => 5Fe⁺³ + Mn⁺² + 4H₂O

Explanation:

Fe⁺² + MnO₄⁻ +  H⁺ => Mn⁺² + Fe⁺³ +  H₂O

5(Fe⁺² => Fe⁺³ + 1e⁻)      =>                        5Fe⁺² => 5Fe⁺³ + 5e⁻

<u>MnO₄⁻ + 5e⁻ => Mn⁺²    =>   MnO₄⁻ + 8H⁺ + 5e⁻ => Mn⁺² + 4H₂O</u>

                                      =>  5Fe⁺² + MnO₄⁻ + 8H⁺ => 5Fe⁺³ + Mn⁺² + 4H₂O

6 0
3 years ago
Calculate the mass of sucrose needed to prepare a 2000 grams of 2.5% sucrose solution.
meriva

Answer:

50 g Sucrose

Explanation:

Step 1: Given data

  • Mass of solution: 2000 g
  • Concentration of the solution: 2.5%

Step 2: Calculate the mass of sucrose needed to prepare the solution

The concentration of the solution is 2.5%, that is, there are 2.5 g of sucrose (solute) every 100 g of solution. The mass of sucrose needed to prepare 2000 g of solution is:

2000 g Solution × 2.5 g Sucrose/100 g Solution = 50 g Sucrose

5 0
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In the bromination of arenes, which of the following statements regarding the reaction is true?a.The hydrocarbon is used in exce
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The hydrocarbon is used in excess.

<h3><u>Explanation</u>:</h3>

The bromination of an arene is not simple as bromination of an alkane. This is because the carbocation or free radicle formation in benzene is a very energy consuming process. This is why a lewis base like aluminium bromide or ferric bromide is used. The ferric bromide takes in the bromine radicle and forms the brominium cation which helps in the formation of electrophile. Now this electrophile brominium cation attacks the benzene ring and forms a temporary sp3 hybrid carbon intermediate. Then the hydrogen is taken by the FeBr4- forming HBr and regenerating the FeBr3 as well as Aromaticity of the arene species at the same time. Here hydrocarbon is used in excess just to prevent the chances of multiple substitution in the same arene molecule.

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