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kirill [66]
2 years ago
13

As atomic size increases, how do electronegativity and ionization energy change?

Chemistry
1 answer:
makkiz [27]2 years ago
3 0
Ionisation of energy is the amount of energy needed to remove an electron from outer most shell of an atom. as the attraction between the nucleus and outer most electron increases the ionisation energy increases. Electronegativity is the relative measure of the force of attraction between an atom and the electron it is sharing in bond with other atom. electronegativity decreases as it goes down the group. 

In conclusion:

As an atom gain an electron the atomic radius of the atom increase and the ionisation energy also increases but the electronegativity decrease as the atoms in outer most shell move further apart from the nucleus.
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What is the vapor pressure of the solution if 35.0 g of water is dissolved in 100.0 g of ethyl alcohol at 25 ∘C? The vapor press
masya89 [10]

<u>Answer:</u> The vapor pressure of the solution is 43.55 mmHg

<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}      .....(1)

  • <u>For water:</u>

Given mass of water = 35.0 g

Molar mass of water = 18 g/mol

Putting values in equation 1, we get:

\text{Moles of water}=\frac{35.0g}{18g/mol}=1.944mol

  • <u>For ethyl alcohol:</u>

Given mass of ethyl alcohol = 100.0 g

Molar mass of ethyl alcohol = 46 g/mol

Putting values in equation 1, we get:

\text{Moles of ethyl alcohol}=\frac{100.0g}{46g/mol}=2.174mol

Total moles of solution = [1.944 = 2.174] moles = 4.118 moles

  • Mole fraction of a substance is given by:

\chi_A=\frac{n_A}{n_A+n_B}

<u>For water:</u>

\chi_{\text{water}}=\frac{n_{\text{water}}}{n_{\text{water}}+n_{\text{ethyl alcohol}}}

\chi_{water}=\frac{1.944}{4.118}=0.472

<u>For ethyl alcohol:</u>

\chi_{\text{ethyl alcohol}}=\frac{n_{\text{ethyl alcohol}}}{n_{\text{water}}+n_{\text{ethyl alcohol}}}

\chi_{\text{ethyl alcohol}}=\frac{2.174}{4.118}=0.528

Dalton's law of partial pressure states that the total pressure of the system is equal to the sum of partial pressure of each component present in it.

To calculate the vapor pressure of the solution, we use the law given by Dalton, which is:

P_T=\sum_{i=1}^n (p_i\times \chi_i)

Or,

P_T=[(p_{\text{water}}\times \chi_{\text{water}})+(p_{\text{ethyl alcohol}}\times \chi_{\text{ethyl alcohol}}

We are given:

Vapor pressure of water = 23.8 mmHg

Vapor pressure of ethyl alcohol = 61.2 mmHg

Putting values in above equation, we get:

p_T=[(23.8\times 0.472)+(61.2\times 0.528)]\\\\p_T=43.55mmHg

Hence, the vapor pressure of the solution is 43.55 mmHg

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