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vampirchik [111]
3 years ago
5

If the solvent front is 68 mm and the ring front of an unknown is 48mm from the original spot, what is the rf value?

Chemistry
1 answer:
Nat2105 [25]3 years ago
3 0

<u>Given:</u>

Distance of solvent front = 68 mm

Distance of unknown = 48 mm

<u>To determine:</u>

The rf value

<u>Explanation:</u>

The retention factor or the rf value is given by the ratio of distance traveled by the unknown to the distance traveled by the solvent front

RF = distance by unknown/distance by solvent

RF = 48/68 = 0.706

Ans: the RF value is 0.706

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Some SbCl5 is allowed to dissociate into SbCl3 and Cl2 at 521 K. At equilibrium, [SbCl5] = 0.195 M, and [SbCl3] = [Cl2] = 6.98×1
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a) The equilibrium will shift in the right direction.

b) The new equilibrium concentrations after reestablishment of the equilibrium :

[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M

[SbCl_3]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M

[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M

Explanation:

SbCl_5(g)\rightleftharpoons SbCl_3(g) + Cl_2(g)

a) Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.

This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.

On increase in amount of reactant

SbCl_5(g)\rightleftharpoons SbCl_3(g) + Cl_2(g)

If the reactant is increased, according to the Le-Chatlier's principle, the equilibrium will shift in the direction where more product formation is taking place. As the number of moles of SbCl_5 is  increasing .So, the equilibrium will shift in the right direction.

b)

SbCl_5(g)\rightleftharpoons SbCl_3(g) + Cl_2(g)

Concentration of SbCl_5  = 0.195 M

Concentration of SbCl_3  = 6.98\times 10^{-2} M

Concentration of Cl_2  = 6.98\times 10^{-2} M

On adding more [SbCl_5 to 0.370 M at equilibrium :

SbCl_5(g)\rightleftharpoons SbCl_3(g) + Cl_2(g)

Initially

0.370 M         6.98\times 10^{-2}M    

At equilibrium:

(0.370-x)M   (6.98\times 10^{-2}+x)M  

The equilibrium constant of the reaction  = K_c

K_c=2.50\times 10^{-2}

The equilibrium expression is given as:

K_c=\frac{[SbCl_3][Cl_2]}{[SbCl_5]}

2.50\times 10^{-2}=\frac{(6.98\times 10^{-2}+x)M\times (6.98\times 10^{-2}+x)M}{(0.370-x) M}

On solving for x:

x = 0.0233 M

The new equilibrium concentrations after reestablishment of the equilibrium :

[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M

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[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M

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3 years ago
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