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vampirchik [111]
3 years ago
5

If the solvent front is 68 mm and the ring front of an unknown is 48mm from the original spot, what is the rf value?

Chemistry
1 answer:
Nat2105 [25]3 years ago
3 0

<u>Given:</u>

Distance of solvent front = 68 mm

Distance of unknown = 48 mm

<u>To determine:</u>

The rf value

<u>Explanation:</u>

The retention factor or the rf value is given by the ratio of distance traveled by the unknown to the distance traveled by the solvent front

RF = distance by unknown/distance by solvent

RF = 48/68 = 0.706

Ans: the RF value is 0.706

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mass of diphenylacetylene (C_{14}H_{10}) = 0.5297 g

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= 0.002972 mol

By applying the law of calorimeter;

Heat liberated by 0.002972 mole of diphenylacetylene (C_{14}H_{10})  = Heat absorbed by H_2O + Heat absorbed  by the calorimeter

Heat liberated  by 0.002972 mole of diphenylacetylene (C_{14}H_{10})  =  msΔT + cΔT

= 1369 g  × 4.184 J g⁻¹°C⁻¹ × (26.05 - 22.95)°C + 916.9 J/°C (26.05 - 22.95)°C

= 17756.48 J + 2842.39 J

= 20598.87 J

Heat liberated by 0.002972 mole of diphenylacetylene (C_{14}H_{10})  = 20598.87 J

Heat liberated by 1 mole of  diphenylacetylene (C_{14}H_{10}) will be = \frac{20598.87 \ J}{0.002972 \ mol}

= 6930979.139 J/mol

= 6930.98 kJ/mol

Since heat is liberated ; Then, the Molar heat of  Combustion  of  diphenylacetylene (C_{14}H_{10})  = -6.931 *10^3 \ kJ/mol

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