<span>bright yellow light and lots of heat-energy.</span>
To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
From the calculation, the standard free energy of the system is -359kJ.
<h3>What is the standard free-energy?</h3>
The standard free-energy is the energy present in the system. We have to first obtain the cell potential using the formula;
Ereduction - E oxidation = 0.96 V - 0.34 V = 0.62 V
Using the formula;
ΔG = -nFEcell
ΔG =-(6 * 96500 * 0.62)
ΔG =-359kJ
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Answer:
yes
Explanation:islands and mountains
The number of grams of Cl2 formed when 0.385 mol HCl reacts with an excess of O2 is 13.6675 g.
<h3>What are moles?</h3>
A mole is defined as 6.02214076 ×
of some chemical unit, be it atoms, molecules, ions, or others. The mole is a convenient unit to use because of the great number of atoms, molecules, or others in any substance.
Given data:
Moles of hydrochloric acid = 0.385 mol
Mass of chlorine gas =?
Chemical equation:
4HCl + O₂ → 2Cl₂ + 2H₂O
Now we will compare the moles of Cl₂ with HCl.
HCl : Cl₂
4 : 2
0.385 : 2÷4× 0.385 = 0.1925 mol
Oxygen is present in excess that's why the mass of chlorine produced depends upon the available amount of HCl.
Mass of Cl₂ :
Mass of Cl₂ = moles × molar mass
Mass of Cl₂ =0.1925 mol × 71 g/mol
Mass of Cl₂ = 13.6675 g
Hence, the number of grams of Cl2 formed when 0.385 mol HCl reacts with an excess of O2 is 13.6675 g.
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