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Serga [27]
3 years ago
8

How much faster does nitrogen monoxide (NO) effuse in comparison to dinitrogen tetraoxide (N2O4)?

Chemistry
1 answer:
juin [17]3 years ago
5 0

Answer:

N5O2

Explanation:

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How much NaCl would you dissolve and dilute to the 100.00 mL mark in a volumetric flask with DI H2O to prepare a 0.825 M sodium
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10. A 20.00 mL sample of 0.150 mol/L ammonia (NH3(aq)) is titrated to the equivalence point by 20.0 mL of a solution of 0.150 mo
Natalija [7]

Answer:

\large \boxed{\rm a)\, NH_{3}(aq) + \text{HI}(aq) \, \longrightarrow \, \,$ NH_{4}^{+}(aq) +\text{I}^{-}(aq);\,b)\,11.22;\, c)\, 5.19}

Explanation:

a) Balanced equation

The balanced chemical equation for the titration is

\large \boxed{\rm NH_{3}(aq) + \text{HI}(aq) \, \longrightarrow \, \,$ NH_{4}^{+}(aq) +\text{I}^{-}(aq)}

b) pH at start

For simplicity, let's use B as the symbol for NH₃.

The equation for the equilibrium is

\rm B + H_{2}O \, \rightleftharpoons\,BH^{+} + OH^{-}

(i) Calculate [OH]⁻

We can use an ICE table to do the calculation.

                      B + H₂O ⇌ BH⁺ + OH⁻

I/mol·L⁻¹:     0.150               0         0

C/mol·L⁻¹:       -x                 +x       +x

E/mol·L⁻¹:  0.150 - x            x          x

K_{\text{b}} = \dfrac{\text{[BH}^{+}]\text{[OH}^{-}]}{\text{[B]}} = 1.8 \times 10^{-5}\\\\\dfrac{x^{2}}{0.150 - x} = 1.8 \times 10^{-5}

Check for negligibility:

\dfrac{0.150 }{1.8 \times 10^{-5}} = 8300 > 400\\\\x \ll 0.150

(ii) Solve for x

\dfrac{x^{2}}{0.150} = 1.8 \times 10^{-5}\\\\x^{2} = 0.150 \times 1.8 \times 10^{-5}\\x^{2} = 2.7 \times 10^{-6}\\x = \sqrt{2.7 \times 10^{-6}}\\x = \text{[OH]}^{-} = 1.64 \times 10^{-3} \text{ mol/L}

(iii) Calculate the pH

\text{pOH} = -\log \text{[OH}^{-}] = -\log(1.64 \times 10^{-3}) = 2.78\\\\\text{pH} = 14.00 - \text{pOH} = 14.00 - 2.78 = \mathbf{11.22}\\\\\text{The pH of the solution at equilibrium is } \large \boxed{\mathbf{11.22}}

(c) pH at equivalence point

(i) Calculate the moles of each species

\text{Moles of B} = \text{Moles of HI} = \text{20.00 mL} \times \dfrac{\text{0.0150 mmol}}{\text{1 mL}} = \text{3.00 mmol}

                 B    +    HI   ⇌   BH⁺ + I⁻

I/mol:       3.00    3.00         0

C/mol:    -3.00   -3.00     +3.00

E/mol/:       0          0          3.00

(ii) Calculate the concentration of BH⁺

At the equivalence point we have a solution containing 3.00 mmol of NH₄I

Volume = 20.00 mL + 20.00 mL = 40.00 mL

\rm [BH^{+}] = \dfrac{\text{3.00 mmol}}{\text{40.00 mL}} = \text{0.0750 mol/L}

(iii) Calculate the concentration of hydronium ion

We can use an ICE table to organize the calculations.

                      BH⁺+ H₂O ⇌ H₃O⁺ +  B

I/mol·L⁻¹:     0.0750                 0        0

C/mol·L⁻¹:        -x                     +x      +x

E/mol·L⁻¹:   0.0750 - x             x         x

K_{\text{a}} = \dfrac{K_{\text{w}}} {K_{\text{b}}} = \dfrac{1.00 \times 10^{-14}}{1.8 \times 10^{-5}} = 5.56 \times 10^{-10}\\\\\dfrac{x^{2}}{0.0750 - x} = 5.56 \times 10^{10}\\\\\text{Check for negligibility of }x\\\dfrac{0.0750}{5.56 \times 10^{-10}} = 1.3 \times 10^{6} > 400\\\\\therefore x \text{ $\ll$ 0.0750}

\dfrac{x^{2}}{0.0750} = 5.56 \times 10^{-10}\\\\x^{2} = 0.0750 \times 5.56 \times 10^{-10}\\x^{2} = 4.17 \times 10^{-11}\\x = \sqrt{4.17 \times 10^{-11}}\\\rm [H_{3}O^{+}] =x = 6.46 \times 10^{-6}\, mol \cdot L^{-1}

(iv) Calculate the pH

\text{pH} = -\log{\rm[H_{3}O^{+}]} = -\log{6.46 \times 10^{-6}} = \large \boxed{\mathbf{5.19}}

The titration curve below shows the pH at the beginning and at the equivalence point of the titration.

8 0
3 years ago
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