Question

Which reactant should be used to convert propene to 1,2-dichloropropane?

Answer 1

Propene +cl2 -> 1,2 dichloropropane

Answer 2

Answer:

Reactant is shown below

Explanation:

• To convert propene to 1,2-dichloropropane, $Cl_{2}$ should be used in a polar aprotic slovent like $CH_{2}Cl_{2}$.
• Here, $Cl_{2}$ adds onto double bond and forms a chloronium cation followed by nucleophilic attack by a chloride ion.
• Chloronium ion intermediate has transient carbocationic character, Therefore chloride ion attack at more substituted position.
• Reaction mechanism has been shown below.