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yawa3891 [41]
3 years ago
5

A piece of gold with a mass of 15.23g and an initial temp of 53 Celsius was dropped into a calorimeter containing 28g of water,

the final temp of the metal and water in the calorimeter was 62 what is the initial temp
Chemistry
1 answer:
Vika [28.1K]3 years ago
6 0

Answer : The initial temperature of water (in ^{0}celcius) = 77.108^{0}C  

Solution : Given,

Mass of gold = 15.23 g

Mass of water = 28 g

Initial temperature of gold = 53^{0}C  

Final temperature of gold = 62^{0}C

Final temperature of water = 62^{0}C

Heat capacity of gold = 12.9J/g^{0}C

Heat capacity of water = 4.18J/g^{0}C

The formula used for calorimetry is,

q = m × c × ΔT

where,

q = heat required

m = mass of an element

c = heat capacity

ΔT = change in temperature

In the calorimetry, the energy as heat lost by the system is equal to the gained by the surroundings.

Now the above formula converted and we get

q_{system}= - q_{surrounding}

m_{system}\times c_{system}\times (T_{final}-T_{initial})_{system}= -[m_{surrounding}\times c_{surrounding}\times (T_{final}-T_{initial})_{surrounding}]

m_{gold}\times c_{gold}\times (T_{final}-T_{initial})_{gold}= -[m_{water}\times c_{water}\times (T_{final}-T_{initial})_{water}]

Now put all the given values in this formula, we get

15.23g\times 12.9J/g^{0}C \times (62^{0}C-53^{0}C )= -[28g\times 4.18J/g^{0}C \times (62^{0}C-T_{\text{ initial of water}})]

By rearranging the terms, we get

T_{\text{ initial water}=77.108^{0}C

Thus the initial temperature of water = 77.108^{0}C  

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Given the following two quantities: 0.50 mol of CH4 and 1.0 mol of HCl,
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Answer:

(a) HCl

(b) HCl

(c) HCl

(d) HCl

Explanation:

<em>Given: </em>0.50 mol of CH₄ and 1.0 mol of HCl

Using stoichiometry we can calculate the answers to parts a, b, c, and d.

<h3>Part (a) </h3>

# of moles × Avogadro's number = # of atoms or molecules

Avogadro's number: 6.02 * 10²³

  • \displaystyle 0.50\ \text{mol CH}_4 \cdot \frac{6.02\cdot 10^2^3 \ \text{atoms CH}_4}{1 \ \text{mol CH}_4} = 3.01 \cdot 10^2^3 \ \text{atoms CH}_4
  • \displaystyle 1.0\ \text{mol HCl} \cdot \frac{6.02\cdot 10^2^3 \ \text{atoms HCl}}{1 \ \text{mol HCl}} = 6.02 \cdot 10^2^3 \ \text{atoms HCl}

HCl has more atoms than CH₄.

<h3>Part (b) </h3>

This is calculated the same way as Part (a); HCl has more molecules than CH₄.

<h3>Part (c) </h3>

Molar mass of CH₄ = 16.04 g/mol

Molar mass of HCl = 36.458 g/mol

  • \displaystyle 0.50\ \text{mol CH}_4 \cdot \frac{16.04 \ \text{g CH}_4}{1 \ \text{mol CH}_4} = 8.02 \ \text{g CH}_4
  • \displaystyle 1.0\ \text{mol HCl} \cdot \frac{36.458 \ \text{g HCl}}{1 \ \text{mol HCl}} = 36.458 \ \text{g HCl}

HCl has a greater mass than CH₄.

<h3>Part (d)</h3>

Assuming STP:

Molar volume of any gas at STP is 22.4 L/mol.

  • \displaystyle 0.50\ \text{mol CH}_4 \cdot \frac{22.4 \ \text{L CH}_4}{1 \ \text{mol CH}_4} = 11.2 \ \text{L CH}_4
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