Answer:
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Answer:
The reaction will be non spontaneous at these concentrations.
Explanation:

Expression for an equilibrium constant
:
![K_c=\frac{[Ag^+][Br^-]}{[AgCl]}=\frac{[Ag^+][Br^-]}{1}=[Ag^+][Br^-]](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BAg%5E%2B%5D%5BBr%5E-%5D%7D%7B%5BAgCl%5D%7D%3D%5Cfrac%7B%5BAg%5E%2B%5D%5BBr%5E-%5D%7D%7B1%7D%3D%5BAg%5E%2B%5D%5BBr%5E-%5D)
Solubility product of the reaction:
![K_{sp}=[Ag^+][Br^-]=K_c=7.7\times 10^{-13}](https://tex.z-dn.net/?f=K_%7Bsp%7D%3D%5BAg%5E%2B%5D%5BBr%5E-%5D%3DK_c%3D7.7%5Ctimes%2010%5E%7B-13%7D%20)
Reaction between Gibb's free energy and equilibrium constant if given as:


![\Delta G^o=-2.303\times 8.314 J/K mol\times 298 K\times \log[7.7\times 10^{-13}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo%3D-2.303%5Ctimes%208.314%20J%2FK%20mol%5Ctimes%20298%20K%5Ctimes%20%5Clog%5B7.7%5Ctimes%2010%5E%7B-13%7D%5D)

Gibb's free energy when concentration
and ![[Br^-] = 1.0\times 10^{-3} M](https://tex.z-dn.net/?f=%5BBr%5E-%5D%20%3D%201.0%5Ctimes%2010%5E%7B-3%7D%20M)
Reaction quotient of an equilibrium = Q
![Q=[Ag^+][Br^-]=1.0\times 10^{-2} M\times 1.0\times 10^{-3} M=1.0\times 10^{-5}](https://tex.z-dn.net/?f=Q%3D%5BAg%5E%2B%5D%5BBr%5E-%5D%3D1.0%5Ctimes%2010%5E%7B-2%7D%20M%5Ctimes%201.0%5Ctimes%2010%5E%7B-3%7D%20M%3D1.0%5Ctimes%2010%5E%7B-5%7D)

![\Delta G=69.117 kJ/mol+(2.303\times 8.314 Joule/mol K\times 298 K\times \log[1.0\times 10^{-5}])](https://tex.z-dn.net/?f=%5CDelta%20G%3D69.117%20kJ%2Fmol%2B%282.303%5Ctimes%208.314%20Joule%2Fmol%20K%5Ctimes%20298%20K%5Ctimes%20%5Clog%5B1.0%5Ctimes%2010%5E%7B-5%7D%5D%29)

- For reaction to spontaneous reaction:
. - For reaction to non spontaneous reaction:
.
Since ,the value of Gibbs free energy is greater than zero which means reaction will be non spontaneous at these concentrations
Longer than visable light
<u>Answer:</u> The volume of concentrated solution required is 9.95 mL
<u>Explanation:</u>
To calculate the pH of the solution, we use the equation:
![pH=-\log[H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%5BH%5E%2B%5D)
We are given:
pH = 0.70
Putting values in above equation, we get:
![0.70=-\log[H^+]](https://tex.z-dn.net/?f=0.70%3D-%5Clog%5BH%5E%2B%5D)
![[H^+]=10^{-0.70}=0.199M](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%3D10%5E%7B-0.70%7D%3D0.199M)
1 mole of nitric acid produces 1 mole of hydrogen ions and 1 mole of nitrate ions.
Molarity of nitric acid = 0.199 M
To calculate the volume of the concentrated solution, we use the equation:

where,
are the molarity and volume of the concentrated nitric acid solution
are the molarity and volume of diluted nitric acid solution
We are given:

Putting values in above equation, we get:

Hence, the volume of concentrated solution required is 9.95 mL