To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
Answer:
The enthalpy of reaction for the reaction of chlorine with ozone is -162.5 kJ.
Explanation:
..[1]
..[2]
..[3]
The enthalpy of reaction for the reaction of chlorine with ozone can be calculated by using Hess's law:
[2] - [1] = [3]
The enthalpy of reaction for the reaction of chlorine with ozone is -162.5 kJ.
2Ca + O2 = 2CaO
First, determine which is the excess reactant
72.5 g Ca (1 mol) =1.8089725036
(40.078 g)
65 g O2 (1 mol) =2.0313769611
(15.999g × 2)
Since the ratio of to O2 is 2:1 in the balanced reaction, divide Ca's molar mass by 2 to get 0.9044862518. this isn't necessary because Ca is already obviously the limiting reactant. therefore, O2 is the excess reactant.
Now do the stoichiometry
72.5 g Ca (1 mol Ca) (1 mol O2)
(40.078 g Ca)(2 mol Ca)(31.998g O2)
=0.0282669621 g of O2 left over
Chemical properties can be determined by heat combustion, how they react with other chemicals, Oxidization (lose electrons, losing hydrogen, gaining oxygen), or toxicity.
