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Harman [31]
3 years ago
9

Give all possible ml values for orbitals that have each of the following: (a) l = 2; (b) n = 1; (c) n = 4, l = 3.

Chemistry
1 answer:
Olin [163]3 years ago
7 0

Answer:

(a) ml = 0, ±1, ±2

(b) ml = 0

(c) ml = 0, ±1, ±2, ±3, ±4

Explanation:

The rules for electron quantum numbers are:

1. Shell number, 1 ≤ n

2. Subshell number, 0 ≤ l ≤ n − 1

3. Orbital energy shift, -l ≤ ml ≤ l

4. Spin, either -1/2 or +1/2

So in our exercise,

(a) l = 2; equivalent with with sublevel <em>d</em>

-l ≤ ml ≤ l, ml = 0, ±1, ±2, equivalent with dxy, dxz, dyz, dx2-y2, dz2

(b) n = 1;

n = 1, only 01 level

l = 0, equivalent with sublevel <em>s</em>

ml = 0

(c) n = 4, l = 3.

l = 3, equivalent with sublevel <em>f</em>

ml = 0, ±1, ±2, ±3, ±4

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When 0.250 moles of KCl are added to 200.0 g of water in a constant pressure calorimeter a temperature change is observed. Given
777dan777 [17]

Explanation:

Upon dissolution of KCl heat is generated and temperature of the solution raises.

Therefore, heat generated by dissolving 0.25 moles of KCl will be as follows.

             17.24 kJ/mol \times 0.25 mol

                = 4.31 kJ

or,             = 4310 J      (as 1 kJ = 1000 J)

Mass of solution will be the sum of mass of water and mass of KCl.

       Mass of Solution = mass of water + (no. of moles of KCl × molar mass)

                                    = 200 g + (0.25 mol \times 54.5 g/mol)

                                    = 200 g + 13.625 g

                                    = 213.625 g

Relation between heat, mass and change in temperature is as follows.

                             Q = mC \Delta T

where,    C = specific heat of water = 4.184 J/g^{o}C

Therefore, putting the given values into the above formula as follows.

                     Q = mC \Delta T

            4310 J = 213.625 g \times 4.184 J/g^{o}C \times \Delta T      

              \Delta T = 4.82^{o}C

Thus, we can conclude that rise in temperature will be 4.82^{o}C.

6 0
3 years ago
A radioactive material, with half-life of six months, has 100 thousand unstable nuclei.
goldfiish [28.3K]

Answer:

See Explanation

Explanation:

Given that;

N/No = (1/2)^t/t1/2

Where;

No = amount of radioactive isotope originally present

N = A mount of radioactive isotope present at time t

t = time taken

t1/2 = half life

N/1000=(1/2)^3/6

N/1000=(1/2)^0.5

N = (1/2)^0.5 * 1000

N= 707 unstable nuclei

Since the value of the initial activity of the radioactive material was not given, the activity of the radioactive material after three months is given by;

Decay constant = 0.693/t1/2 = 0.693/6 months = 0.1155 month^-1

Hence;

A=Aoe^-kt

Where;

A = Activity after a time t

Ao = initial activity

k = decay constant

t = time taken

A = Aoe^-3 *0.1155

A=Aoe^-0.3465

3 0
3 years ago
What does vinegar do to eggs
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Eggshells are made primarily of calcium carbonate. The acid in vinegar softens the calcium of the eggshell. Adding a little vinegar to the water when boiling eggs is an old cook’s trick that makes them easier to peel.

A link to this experiment is below in the comment box


7 0
3 years ago
When 2 moles of Fe(s) react with Cl2(g) to form FeCl3(s) according to the following equation, 799 kJ of energy are evolved.
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Answer:

1. Exothermic.

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Explanation:

Hello!

1. In this case, according to the reaction, we can infer that 799 kJ of energy are evolved (given off, released) it means that the enthalpy of reaction is negative as the reactants have more energy than the products; which means this is an exothermic reaction.

2. Here, as we know that the enthalpy of reaction is -799 kJ/mol, we can compute the q-value as shown below, considering the reacted 2 moles of solid iron:

q=2mol*-799 kJ/mol\\\\q=-1598kJ

Which means that 1598 kJ of energy are evolved when 2 moles of solid iron react.

Best regards!

4 0
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Answer:

B.

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