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Kaylis [27]
2 years ago
9

What is the correlation between pressure and elevation for an ideal gas?

Chemistry
1 answer:
deff fn [24]2 years ago
7 0

Explanation:

Expression for vertical fluid pressure is as follows.

               \frac{dP}{dh} = \rho \times g ........... (1)

where,     p = pressure

            \rho = density

               g = acceleration due to gravity

               h = height

Since, g is negative then it means that an increase in height will lead to decrease in pressure.

Also, expression for density according to ideal gas law is as follows.

                 \rho = \frac{mP}{kT} .......... (2)

where,         m = average mass or air molecule

                    P = pressure at a given point

                    k = Boltzmann constant

                    T = temperature in kelvin

Substituting values from equation (2) into equation (1) as follows.

              \frac{dP}{dh} = \rho \times g

              \frac{dP}{dh} = \frac{mP}{kT} \times g

               \frac{dP}{P} =  \frac{mg}{kT}dh

Now, on applying integration on both the sides we get the following.

                    ln\frac{P_{h}}{P^{o}} = \frac{-mgh}{kT}

or,                          P_{h} = P_{o}e^{\frac{-mgh}{kT}}                    

where,           P_{h} = pressure at height h

                      P_{o} = pressure at reference point    

Thus, we can conclude that the correlation between pressure and elevation for an ideal gas is  P_{h} = P_{o}e^{\frac{-mgh}{kT}}.        

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What volumes of 0.200 M HCOOH and 2.00 M NaOH would make 500. mL of a buffer with the same pH as one made from 475 mL of 0.200 M
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<u>36 ml of NaOh and</u><u> 464 ml</u><u> of </u><u>HCOOH</u><u> would be enough to form 500 ml of a buffer with the same pH as the buffer made with </u><u>benzoic acid </u><u>and NaOH.</u>

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Calculate the amount of moles in NaOH and benzoic acid. This calculation is done by multiplying molarity by volume.

Amount of moles of NaOH -2 × 0.025 =  0.05 mol

Amount of moles of benzoic acid 2 × 0.475 = 0.095 mol

In this case, we can calculate the pH produced by the buffer of these two reagents, as follows

pH = pKa + log\frac{base}{acid}

4.2 + log\frac{0.05}{0.045} = 4.245

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pH = pKa + log\frac{base}{acid}

4.245 = 3.75 + log\frac{base}{acid}

log\frac{base}{acid} = 0.5

\frac{base}{acid} = 3.162

Now we must solve the equation above. This will be done using the following values

\frac{2(0.5 - x)}{0.2x - 2(0.5 - x)} = 0.464 L

With these values, we can calculate the volumes of NaOH and HCOOH needed to make the buffer.

NaOH volume

( 0.5 - 0.464)L

0.036L .................... 36ml

HCOOH volume

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