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Kaylis [27]
3 years ago
9

What is the correlation between pressure and elevation for an ideal gas?

Chemistry
1 answer:
deff fn [24]3 years ago
7 0

Explanation:

Expression for vertical fluid pressure is as follows.

               \frac{dP}{dh} = \rho \times g ........... (1)

where,     p = pressure

            \rho = density

               g = acceleration due to gravity

               h = height

Since, g is negative then it means that an increase in height will lead to decrease in pressure.

Also, expression for density according to ideal gas law is as follows.

                 \rho = \frac{mP}{kT} .......... (2)

where,         m = average mass or air molecule

                    P = pressure at a given point

                    k = Boltzmann constant

                    T = temperature in kelvin

Substituting values from equation (2) into equation (1) as follows.

              \frac{dP}{dh} = \rho \times g

              \frac{dP}{dh} = \frac{mP}{kT} \times g

               \frac{dP}{P} =  \frac{mg}{kT}dh

Now, on applying integration on both the sides we get the following.

                    ln\frac{P_{h}}{P^{o}} = \frac{-mgh}{kT}

or,                          P_{h} = P_{o}e^{\frac{-mgh}{kT}}                    

where,           P_{h} = pressure at height h

                      P_{o} = pressure at reference point    

Thus, we can conclude that the correlation between pressure and elevation for an ideal gas is  P_{h} = P_{o}e^{\frac{-mgh}{kT}}.        

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The correct option is e.

Explanation:

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Acenapthalene has the empirical formula C6H5. A solution of 0.515 g of acenapthalene in 15.0 g CHCl3 boils at 62.5oC. The normal
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Answer:

The molecular formula of an ascenapthalene is C_{12}H_{10}

Explanation:

\Delta T_b=K_b\times m

\Delta T_b=K_b\times \frac{\text{Mass of acenapthalene}}{\text{Molar mass of acenapthalene}\times \text{Mass of chloroform in Kg}}

where,

\Delta T_f =Elevation in boiling point = (62.5-61.7)^oC=0.8^oC

Mass of acenapthalene = 0.515 g

Mass of CHCl_3 = 15.0 g = 0.015 kg (1 kg = 1000 g)

K_b = boiling point constant = 3.63 °C/m

m = molality

Now put all the given values in this formula, we get

0.8^0C=3.67 ^oC/m\times \frac{0.515}{\text{Molar mass of acenapthalene}\times 0.015kg}

\text{Molar mass of acenapthalene}=155.7875 g/mol

Let the molecule formula of the Acenapthalene be C_{6n]H_{5n}

6n\times 12 g/mol+5n\times 1 g/mol=155.7875 g/mol

n = 2.0

The molecular formula of an ascenapthalene is C_{12}H_{10}

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