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Kaylis [27]
3 years ago
9

What is the correlation between pressure and elevation for an ideal gas?

Chemistry
1 answer:
deff fn [24]3 years ago
7 0

Explanation:

Expression for vertical fluid pressure is as follows.

               \frac{dP}{dh} = \rho \times g ........... (1)

where,     p = pressure

            \rho = density

               g = acceleration due to gravity

               h = height

Since, g is negative then it means that an increase in height will lead to decrease in pressure.

Also, expression for density according to ideal gas law is as follows.

                 \rho = \frac{mP}{kT} .......... (2)

where,         m = average mass or air molecule

                    P = pressure at a given point

                    k = Boltzmann constant

                    T = temperature in kelvin

Substituting values from equation (2) into equation (1) as follows.

              \frac{dP}{dh} = \rho \times g

              \frac{dP}{dh} = \frac{mP}{kT} \times g

               \frac{dP}{P} =  \frac{mg}{kT}dh

Now, on applying integration on both the sides we get the following.

                    ln\frac{P_{h}}{P^{o}} = \frac{-mgh}{kT}

or,                          P_{h} = P_{o}e^{\frac{-mgh}{kT}}                    

where,           P_{h} = pressure at height h

                      P_{o} = pressure at reference point    

Thus, we can conclude that the correlation between pressure and elevation for an ideal gas is  P_{h} = P_{o}e^{\frac{-mgh}{kT}}.        

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Mathematical expression:

P₁V₁ = P₂V₂

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Now we will put the values in formula,

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d(C₄H₆O₃) = 1.08 g/mL.
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m(C₄H₆O₃) = 5.00 mL · 1.08 g/mL.
m(C₄H₆O₃) = 5.4 g.
n(C₄H₆O₃) = m(C₄H₆O₃) ÷ M(C₄H₆O₃).
n(C₄H₆O₃) = 5.4 g ÷ 102 g/mol.
n(C₄H₆O₃) = 0.0529 mol.
n(C₇H₆O₃) = 2.08 g ÷ 138.1 g/mol.
n(C₇H₆O₃) = 0.015 mol; limiting reactant.
From chemical reaction: n(C₄H₆O₃) : n(C₉H₈O₄) = 1 : 1.
n(C₉H₈O₄) = 0.015 mol.
m(C₉H₈O₄) = 0.015 mol · 180.16 g/mol.
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