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Ghella [55]
3 years ago
8

How is it that when a salt sample dissolves in water, the delta S for the process is positive?

Chemistry
1 answer:
Bess [88]3 years ago
4 0

Answer:-

Water is highly ordered. In water each oxygen atom is connected to others around it through hydrogen bonding via bridging hydrogen atoms. When a salt like NaCl is dissolved, some of these Hydrogen bonds break.

When a salt like NaCl dissolves in water, the NaCl breaks in to ions Na+ and Cl-.

The water molecules now surround these ions.

The slightly negative oxygen end of water molecule gets near the Na+, while the slightly positive Hydrogen of water molecule gets near the Cl-.

So before salt sample dissolve, the water molecules were highly ordered due to hydrogen bonding. Now after salt dissolve there is a decrease in order and thus an increase in disorder of the water molecules.

Due to increase in disorder, entropy which is a measure of disorder increases. Since entropy increases, delta S for the process is positive.

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butalik [34]

Answer:

0.39 mol

Explanation:

Considering the ideal gas equation as:

PV=nRT

where,  

P is the pressure

V is the volume

n is the number of moles

T is the temperature  

R is Gas constant having value = 0.0821 L.atm/K.mol

At same volume, for two situations, the above equation can be written as:-

\frac {{n_1}\times {T_1}}{P_1}=\frac {{n_2}\times {T_2}}{P_2}

Given ,  

n₁ = 1.50 mol

n₂ = ?

P₁ = 3.75 atm

P₂ = 0.998 atm

T₁ = 21.7  ºC

T₂ = 28.1 ºC

The conversion of T( °C) to T(K) is shown below:

T(K) = T( °C) + 273.15  

So,  

T₁ = (21.7 + 273.15) K = 294.85 K  

T₂ = (28.1 + 273.15) K = 301.25 K  

Using above equation as:

\frac{{n_1}\times {T_1}}{P_1}=\frac{{n_2}\times {T_2}}{P_2}

\frac{{1.50\ mol}\times {294.85\ K }}{3.75\ atm}=\frac{{n_2}\times {301.25\ K  }}{0.998\ atm}

n_2=\frac{{1.50}\times {294.85}\times 0.998}{3.75\times 301.25}\ mol

Solving for n₂ , we get:

n₂ = 0.39 mol

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The precaution to be taken while measuring the temperature of a liquid in a beaker is applying proper heat balance and taking all the required precautions.

  • A beaker with an open top contains a sample of liquid. It exposes this sample to light.
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Learn more about heat balance at:

brainly.com/question/1292905

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