Answer: Option (C) is the correct answer.
Explanation:
Chemical formula of a secondary amide is R'-CONH-R, where R and R' can be same of different alkyl or aryl groups. Here, the hydrogen atom of amide is attached to more electronegative oxygen atom of the C=O group.
Therefore, the hydrogen atom will be more strongly held by the electronegative oxygen atom. As a result, there will be strongly hydrogen bonded in the liquid phase of secondary amide.
Whereas chemical formula of nitriles is RCN, ester is RCOOR' and acid chlorides are RCOCl. As no hydrogen bonding occurs in any of these compounds because hydrogen atom is not being attached to an electronegative atom.
Thus, we can conclude that secondary amides are strongly hydrogen bonded in the liquid phase.
The volume of the 0.279 M Ca(OH)₂ solution required to neutralize 24.5 mL of 0.390 M H₃PO₄ is 51.4 mL
<h3>Balanced equation </h3>
2H₃PO₄ + 3Ca(OH)₂ —> Ca₃(PO₄)₂ + 6H₂O
From the balanced equation above,
- The mole ratio of the acid, H₃PO₄ (nA) = 2
- The mole ratio of the base, Ca(OH)₂ (nB) = 3
<h3>How to determine the volume of Ca(OH)₂ </h3>
- Molarity of acid, H₃PO₄ (Ma) = 0.390 M
- Volume of acid, H₃PO₄ (Va) = 24.5 mL
- Molarity of base, Ca(OH)₂ (Mb) = 0.279 M
- Volume of base, Ca(OH)₂ (Vb) =?
MaVa / MbVb = nA / nB
(0.39 × 24.5) / (0.279 × Vb) = 2/3
9.555 / (0.279 × Vb) = 2/3
Cross multiply
2 × 0.279 × Vb = 9.555 × 3
0.558 × Vb = 28.665
Divide both side by 0.558
Vb = 28.665 / 0.558
Vb = 51.4 mL
Thus, the volume of the Ca(OH)₂ solution needed is 51.4 mL
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