The dissociation of formic acid is:

The acid dissociation constant of formic acid,
is:
![k_a = \frac{[HCOO^{-}] [H^{+}]}{HCOOH}](https://tex.z-dn.net/?f=%20k_a%20%3D%20%5Cfrac%7B%5BHCOO%5E%7B-%7D%5D%20%20%5BH%5E%7B%2B%7D%5D%7D%7BHCOOH%7D%20%20%20%20%20)
Rearranging the equation:
![\frac{[HCOO^{-}]}{[HCOOH]} = \frac{k_a}{[H_+]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BHCOO%5E%7B-%7D%5D%7D%7B%5BHCOOH%5D%7D%20%3D%20%5Cfrac%7Bk_a%7D%7B%5BH_%2B%5D%7D%20)
pH = 2.75
![pH = -log[H^{+}]](https://tex.z-dn.net/?f=%20pH%20%3D%20-log%5BH%5E%7B%2B%7D%5D%20)
![[H^{+}]= 10^{-2.75} = 1.78 \times 10^{-3}](https://tex.z-dn.net/?f=%20%5BH%5E%7B%2B%7D%5D%3D%2010%5E%7B-2.75%7D%20%3D%201.78%20%5Ctimes%2010%5E%7B-3%7D%20)


Substituting the values in the equation:
![\frac{[HCOO^{-}]}{[HCOOH]} = \frac{k_a}{[H_+]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BHCOO%5E%7B-%7D%5D%7D%7B%5BHCOOH%5D%7D%20%3D%20%5Cfrac%7Bk_a%7D%7B%5BH_%2B%5D%7D%20)
![\frac{[HCOO^{-}]}{[HCOOH]} = \frac{1.78\times 10^{-4}}{1.78\times 10^{-3}}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BHCOO%5E%7B-%7D%5D%7D%7B%5BHCOOH%5D%7D%20%3D%20%5Cfrac%7B1.78%5Ctimes%2010%5E%7B-4%7D%7D%7B1.78%5Ctimes%2010%5E%7B-3%7D%7D%20%20%20)
Hence, the ratio is
.
Answer:
+1.03 V
Explanation:
The standard emf of the voltaic cell is the value of the standard potential of it, which is calculated by the standard reduction potential (E°).
The standard reduction potential is the potential needed for the reduction reaction happen, and it's determined by the reaction with the hydrogen cell (which has E° = 0.0V). The half-reactions of reduction of Ni⁺² and Ag⁺, are:
Ni⁺²(aq) + 2e⁻ → Ni(s) E° = -0.23 V
Ag⁺(aq) + e⁻ → Ag(s) E° = +0.80 V
The value is calculated by a spontaneous reaction, in which the cell with the greater E° is reduced (gain electrons), and the other is oxidized (loses electrons). So, Ag⁺ reduces.
emf = E°reduces - E°oxides
emf = 0.80 - (-0.23)
emf = +1.03 V
Answer:
CaCl2 + 2 AgNO3 ---> 2 AgCl + Ca(NO3)2
Answer:
C.) At room temperature and pressure, because intermolecular interactions are minimized and the particles are relatively far apart.
Explanation:
For gas to behave as an ideal gas there are 2 basic assumptions:
- The intermolecular forces (IMF) are neglectable.
- The volume of the gas is neglectable in comparison with the volume of the container.
<em>In which instance is a gas most likely to behave as an ideal gas?</em>
<em>A.) At low temperatures, because the molecules are always far apart.</em> FALSE. At low temperatures, molecules are closer and IMF are more appreciable.
<em>B.) When the molecules are highly polar, because IMF are more likely.</em> FALSE. When IMF are stronger the gas does not behave as an ideal gas.
<em>C.) At room temperature and pressure, because intermolecular interactions are minimized and the particles are relatively far apart.</em> TRUE.
<em>D.) At high pressures, because the distance between molecules is likely to be small in relation to the size of the molecules.</em> FALSE. At high pressures, the distance between molecules is small and IMF are strong.