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Answer:
The new partial pressures after equilibrium is reestablished:



Explanation:

At equilibrium before adding chlorine gas:
Partial pressure of the 
Partial pressure of the 
Partial pressure of the 
The expression of an equilibrium constant is given by :


At equilibrium after adding chlorine gas:
Partial pressure of the 
Partial pressure of the 
Partial pressure of the 
Total pressure of the system = P = 263.0 Torr




At initail
(13.2) Torr (32.8) Torr (13.2) Torr
At equilbriumm
(13.2-x) Torr (32.8-x) Torr (217.0+x) Torr


Solving for x;
x = 6.402 Torr
The new partial pressures after equilibrium is reestablished:



Answer:
See below
Step-by-step explanation:
An exothermic reaction tends to occur spontaneously because the products are more stable than the reactants.
Nature tries to get to the lowest energy state.
Unburned hydrocarbon on reacting with oxygen undergoes combustion reaction. However, the activation energy of this reaction is significantly high. When a catalyst like Pd is added to the reaction system, it provides active sites for the reaction to occur. It acts are a heterogeneous catalyst. It is pertinent of note that catalyst is refereed as heterogeneous, when it exist in different phase as compared to reactant and products. In present case, reactants and products are in gas phase, while catalyst is in solid phase. Due to availability of larger surface area at active site of Pd, activation energy of reaction decreases and decrease in activation energy favors higher reaction rates.
They must obey the Law of Conservation of Mass that states that matter cannot be created or destroyed, it is conserved. Atoms are never lost or gained in chemical reactions, they are rearranged. The mass of the reactants must equal the mass of the products.