Answer:
A. N₂(g) + 3H₂(g) -----> 2NH₃ exothermic
B. S(g) + O₂(g) --------> SO₂(g) exothermic
C. 2H₂O(g) --------> 2H₂(g) + O₂(g) endothermic
D. 2F(g) ---------> F₂(g) exothermic
Explanation:
The question says predict not calculate. So you have to use your chemistry knowledge, experience and intuition.
A. N₂(g) + 3H₂(g) -----> 2NH₃ is exothermic because the Haber process gives out energy
B. S(g) + O₂(g) --------> SO₂(g) is exothermic because it is a combustion. The majority, if not all, combustion give out energy.
C. 2H₂O(g) --------> 2H₂(g) + O₂(g) is endothermic because it is the reverse reaction of the combustion of hydrogen. If the reverse reaction is exothermic then the forward reaction is endothermic
D. 2F(g) ---------> F₂(g) is exothermic because the backward reaction is endothermic. Atomisation is always an endothermic reaction so the forward reaction is exothermic
The rate equation is given as:
k = A e^(- Ea / RT)
Dividing state 1 and state 2:
k1/k2 = e^(- Ea / RT1) / e^(- Ea / RT2)
k1/k2 = e^[- Ea / RT1 - (- Ea / RT2)]
k1/k2 = e^[- Ea / RT1 + Ea / RT2)]
Taking the ln of both sides:
ln (k1/k2) = - Ea / RT1 + Ea / RT2
ln (k1/k2) = - Ea / R (1/T1 - 1/T2)
Since k2 = 4k1, therefore k1/k2 = ¼
ln (1/4) = [- (56,000 J/mol) / (8.314 J / mol K)] (1/273
K – 1/ T2)
2.058 x 10^-4 = 1/273 – 1/T2
T2 = 289.25 K
14. a. Acidic
15. b. Weaker
16. d. Dilute and weak
Explanation:
14. Which type of the solution is one with the pH of 3?
Solution with pH from 1 to 7 are acidic, equal to 7 is neutral and from 7 to 14 basic. The solution with the pH equal to 3 is <u>acidic</u>.
15. The smaller the value of the base dissociation constant (Kb), the <u>weaker</u> the base.
The dissociation reaction of a base (B) is:
B + H₂O → BH⁺ + OH⁻
Kb is defined as:
Kb = ( [BH⁺] × [OH⁻] ) / ( [B] × [H₂O] )
The potency of the base depends on the concentration of the hydroxide ion [OH⁻], so if the Kb ratio is small it means that the concentration of hydroxide ion is smaller so the base will be <u>weaker</u>.
16. A 0.39 M solution of an acid that ionizes only slightly in solution would be termed <u>dilute and weak</u>.
The acid is weak because is only slightly ionizing in solution. The therm diluted is a little bit arbitrarily because we ask yourself "diluted in respect with what"? I would characterize the acid to be diluted at a concentration of 1 M and concentrated at a concentration of 10 M.
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pH
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