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mariarad [96]
3 years ago
7

What is the change in enthalpy in kilojoules when 3.24 g of CH3OH is completely reacted according to the following reaction 2 CH

3OH -->4 CH4 + O2 ∆H
=252.8 Kj
Chemistry
1 answer:
vodka [1.7K]3 years ago
5 0

Answer:

12.78 kJ

Explanation:

The correct balanced reaction would be

2CH_3OH\rightarrow 2CH_4+O_2\Delta H=252.8\ \text{kJ}

Mass of methanol = 3.24\ \text{g}

Moles of methanol can be obtained by dividing the mass of methanol with its molar mass (32.04\ \text{g/mol})

\dfrac{3.24}{32.04}=0.10112\ \text{moles}

Enthalpy change for the number of moles is given by

\dfrac{\text{Number of moles of methanol in the reaction}}{\text{Enthalpy change in the reaction}}=\dfrac{\text{Number of moles in 3.24 g of methanol}}{\text{Enthaply in change in the mass of methanol}}

\\\Rightarrow\dfrac{2}{252.8}=\dfrac{0.10112}{\Delta H}\\\Rightarrow \Delta H=\dfrac{0.10112\times 252.8}{2}\\\Rightarrow \Delta H=12.781568\approx 12.78\ \text{kJ}

The change in enthalpy is 12.78 kJ.

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Which of the following has the strongest buffering capacity? A. H2O B. 0.1 M HCl C. 0.1 M carbonic/bicarbonate (H2CO3/HCO3-) at
enyata [817]

Explanation:

(A)   As we know that carbonic acid (H_{2}CO_{3}) and Sodium bicarbonate (NaHCO_{3}) forms an acidic buffer.

Therefore, pH of an acidic buffer is given by Hendeerson-Hasselbalch equation as follows.

               pH = pK_{a} + log(\frac{[Salt]}{[Acid]}) ........... (1)

So mathematically,  if [Salt] = [Acid]  then \frac{[Salt]}{[Acid]} = 1 .

And,  log (\frac{[Salt]}{[Acid]}) = 0

Therefore, equation (1) gives us the following.

         pH = pK_{a} (when acid and salt are equal in concentration)

Hence, pK_{a} of H_{2}CO_{3} (carbonic acid) is 6.35.

And, with this we have following results.

In (A) and (D) we have the case \frac{[NaHCO_{3}]}{[H_{2}CO_{3}]}[/tex] i.e. [Salt] = [Acid].

Hence, for the cases pH = pK_{a} = 6.35.

(B)    [NaHCO_{3}] = 0.045 M and,  [H_{2}CO_{3}] = 0.45 M

Hence,   pH = 6.35 + log([NaHCO_{3}][[H_{2}CO_{3}])

                     = 6.35 + log(\frac{0.045}{0.45})

                     = 6.35 + (-1)

                     = 5.35

Therefore, it means that this buffer will be most suitable buffer as it has pH on acidic side and addition of slight excess base will not affect much of its pH value.

(C)    [NaHCO_{3}] = 0.45 M [H_{2}CO_{3}]

                          = 0.045 M

So,       pH = 6.35 + log(\frac{[NaHCO_{3}]}{[H_{2}CO_{3}]})

                  = 6.35 + log(\frac{0.45}{0.045})

                  = 6.35 + (+1)

                 = 7.35

This means that pH on Basic side makes it no more acidic buffer.

5 0
3 years ago
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