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butalik [34]
3 years ago
6

The element lanthanum has two stable isotopes, lanthanum-138 with an atomic mass of 137.9 AMU and lanthanum-139 with an atomic m

ass of 138.9 AMU.
From the atomic weight of La = 138.9, one can conclude that:

A. there is an isotope of lanthanum with an atomic mass of 138.9
B. lanthanum-139 has the highest percent natural abundance
C. lanthanum-138 has the highest percent natural abundance
D. both isotopes have the same percent natural abundance
Chemistry
1 answer:
dmitriy555 [2]3 years ago
7 0

Answer:

A. there is an isotope of lanthanum with an atomic mass of 138.9

Explanation:

By knowing the different atomic masses of both Lanthanum atoms, we can not tell anything about their occurence in nature. Therefore, all the last three options are incorrect. Because, the atomic mass does not tell anything about the availability or natural abundance of an element.

Now, the isotopes of an element are those elements, which have same number of electrons and protons as the original element, but different number of neutrons. Therefore, they have same atomic number but, different atomic weight or atomic masses.

Hence, by looking at an elements having same atomic number, but different atomic masses, we can identify them as isotopes.

Thus, the correct option is:

<u>A. there is an isotope of lanthanum with an atomic mass of 138.9.</u>

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II. Ionic Equations
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Answer:

Complete ionic: \begin{aligned}& \rm 2\, Ag^{+}\, (aq) + 2\, {NO_3}^{-} \, (aq) + Ca^{2+}\, (aq) + 2\, Cl^{-}\, (aq) \\ & \rm \to 2\, AgCl\, (s) + Ca^{2+}\, (aq) + 2\, {NO_3}^{-}\, (aq)\end{aligned}.

Net ionic: \begin{aligned}& \rm Ag^{+}\, (aq) + Cl^{-}\, (aq) \to AgCl\, (s)\end{aligned}.

Explanation:

Start by identifying species that exist as ions. In general, such species include:

  • Soluble salts.
  • Strong acids and strong bases.

All four species in this particular question are salts. However, only three of them are generally soluble in water: \rm AgNO_3, \rm CaCl_2, and \rm Ca(NO_3)_2. These three salts will exist as ions:

  • Each \rm AgNO_3\, (aq) formula unit will exist as one \rm Ag^{+} ion and one \rm {NO_3}^{-} ion.
  • Each \rm CaCl_2 formula unit will exist as one \rm Ca^{2+} ion and two \rm Cl^{-} ions (note the subscript in the formula \rm CaCl_2\!.)
  • Each \rm Ca(NO_3)_2 formula unit will exist as one \rm Ca^{2+} and two \rm {NO_3}^{-} ions.

On the other hand, \rm AgCl is generally insoluble in water. This salt will not form ions.

Rewrite the original chemical equation to get the corresponding ionic equation. In this question, rewrite \rm AgNO_3, \rm CaCl_2, and \rm Ca(NO_3)_2 (three soluble salts) as the corresponding ions.

Pay attention to the coefficient of each species. For example, indeed each \rm AgNO_3\, (aq) formula unit will exist as only one \rm Ag^{+} ion and one \rm {NO_3}^{-} ion. However, because the coefficient of \rm AgNO_3\, (aq)\! in the original equation is two, \!\rm AgNO_3\, (aq) alone should correspond to two \rm Ag^{+}\! ions and two \rm {NO_3}^{-}\! ions.

Do not rewrite the salt \rm AgCl because it is insoluble.

\begin{aligned}& \rm 2\, Ag^{+}\, (aq) + 2\, {NO_3}^{-} \, (aq) + Ca^{2+}\, (aq) + 2\, Cl^{-}\, (aq) \\ & \rm \to 2\, AgCl\, (s) + Ca^{2+}\, (aq) + 2\, {NO_3}^{-}\, (aq)\end{aligned}.

Eliminate ions that are present on both sides of this ionic equation. In this question, such ions include one unit of \rm Ca^{2+} and two units of \rm {NO_3}^{-}. Doing so will give:

\begin{aligned}& \rm 2\, Ag^{+}\, (aq) + 2\, Cl^{-}\, (aq) \to 2\, AgCl\, (s)\end{aligned}.

Simplify the coefficients:

\begin{aligned}& \rm Ag^{+}\, (aq) + Cl^{-}\, (aq) \to AgCl\, (s)\end{aligned}.

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