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lidiya [134]
3 years ago
9

How many milliliters of ammonium sulfate solution having a concentration of 0.218 M are needed to react completely with 62.6 ml

of 2.31 M sodium hydroxide solution?
Chemistry
1 answer:
BartSMP [9]3 years ago
6 0

Answer:

330 mL of (NH₄)₂SO₄ are needed

Explanation:

First of all, we determine the reaction:

(NH₄)₂SO₄  +  2NaOH →  2NH₃  +  2H₂O  +  Na₂SO₄

We determine the moles of base:

(First, we convert the volume from mL to L) → 62.6 mL . 1L/1000 mL = 0.0626L

Molarity . volume (L) = 2.31 mol/L . 0.0626 L = 0.144 moles

Ratio is 2:1. Therefore we make a rule of three:

2 moles of hydroxide react with 1 mol of sulfate

Then, 0.144 moles of NaOH must react with (0.144 .1) /2 = 0.072 moles

If we want to determine the volume → Moles / Molarity

0.072 mol / 0.218 mol/L = 0.330 L

We convert from L to mL → 0.330L . 1000 mL/1L = 330 mL

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A solution of 0.0470 M HCl is used to titrate 26.0 mL of an ammonia solution of unknown concentration. The equivalence point is
DanielleElmas [232]

The pH at equivalence point is 12.46

At equivalence point, number of moles of acid, n equals number of moles of base, n'

So, n = n'

CV = C'V' where

  • C = concentration of acid (HCl) = 0.0470 M,
  • V = volume of acid = 16.0 mL,
  • C' = concentration of base (ammonia solution) and
  • V' = volume of base = 26.0 mL.
<h3>Concentration of ammonia solution</h3>

Making C' subject of the formula, we have

C' = CV/V'

Substituting the values of the variables into the equation, we have

C' = CV/V'

C' = 0.0470 M × 16.0 mL/26.0 mL

C' = 0.752 MmL/26.0 mL

C' = 0.0289 M

<h3>The concentration of acid at equivalence point</h3>

We know that the ion-product of water Kw is

Kw = [H⁺][OH⁻] =  where

  • [H⁺] = concentration of HCl at equivalence point,
  • [OH⁻] = C' = concentration of ammonia solution = 0.0289 M and
  • Kw = 1.01 × 10⁻¹⁴

Making [H⁺] subject of the formula, we have

[H⁺} = Kw/[OH⁻]

[H⁺] = 1.01 × 10⁻¹⁴/0.0289

[H⁺] = 34.95 × 10⁻¹⁴

[H⁺] = 3.495 × 10⁻¹³

<h3>pH at equivalence point</h3>

Since pH = -㏒[H⁺]

pH = -㏒[3.495 × 10⁻¹³]

pH = -㏒[3.495] + (-㏒10⁻¹³)

pH = -㏒[3.495] + [-13(-㏒10)]

pH = 13 - 0.5434

pH = 12.4566

pH ≅ 12.46

So, the pH at equivalence point is 12.46

Learn more about pH at equivalence point here:

brainly.com/question/25487920

3 0
2 years ago
What is a covalent bond?
Sphinxa [80]
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hope this helps!
3 0
3 years ago
Which of the following is the correct equation for the reaction below?
fenix001 [56]

Answer:

Option C.

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Explanation:

Two moles of magnesium solid react with one mol of oxygen gas to

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2 Mg (s) + O₂(g) →  2MgO (s)

That's the reaction for the magnessium oxide's formation.

Be careful cause we do not say molecules, they are moles.

The stoichiometry indicates the number of moles that react and the moles which are produced.

It is a redox reaction, because the magnessium is oxidized and the oxygen is reduced. Both elements, changed the oxidation states.

4 0
3 years ago
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Marianna [84]

Answer:

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Explanation:

Using Gay-Lussac's law you get the equation \frac{P1}{T1} x \frac{P2}{T2} and converting celcius you get the final equation of \frac{85.5}{27+273}  x \frac{P2}{127+273} . After dividing 85.5 by 27+273(300) you get 0.285 and then you multiply 0.285 by 127+273 (400). You finally get 114 kPa

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