plz answer 7 & 8 because I dont get the answer... oh and you need to use the picture for the questions 7 & 8 thanks
1 answer:
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Answer:
1,812 wt%
Explanation:
The reactions for this titration are:
2Ce⁴⁺ + 3I⁻ → 2Ce³⁺ + I₃⁻
I₃⁻ + 2S₂O₃⁻ → 3I⁻ + S₄O₆²⁻
The moles in the end point of S₂O₃⁻ are:
0,01302L×0,03428M Na₂S₂O₃ = 4,463x10⁻⁴ moles of S₂O₃⁻. As 2 moles of S₂O₃⁻ react with 1 mole of I₃⁻, the moles of I₃⁻ are:
4,463x10⁻⁴ moles of S₂O₃⁻× = 2,2315x10⁻⁴ moles of I₃⁻
As 2 moles of Ce⁴⁺ produce 1 mole of I₃⁻, the moles of Ce⁴⁺ are:
2,2315x10⁻⁴ moles of I₃⁻× = 4,463x10⁻⁴ moles of Ce(IV). These moles are:
4,463x10⁻⁴ moles of Ce(IV)× = <em>0,0625 g of Ce(IV)</em>
As the sample has a 3,452g, the weight percent is:
0,0625g of Ce(IV) / 3,452g × 100 = <em>1,812 wt%</em>
I hope it helps!
Answer:
Reagent A: PBr₃
Reagent B: Mg in Et₂O.
Explanation:
Hello,
In this case, your facing a problem in which a carboxylic acid is produced starting by an alcohol. More specifically, cyclopentanol must react with phosphorous tribromide in order to yield bromocyclopentane which is more likely to produce a carboxylic acid, therefore, reagent A is PBr₃.
On the other hand, by means of the production of the specified product, bromocyclopentane must react with carbon dioxide and magnesium in diethyl ether in acidic media to promote the production of the cyclopentanoic acid via the grignard reaction (substitution of the bromine by the carboxyle group), therefore, reagent B is Mg in Et₂O.
Best regards.
