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viva [34]
3 years ago
15

NH4NO3, whose heat of solution is 25.7 kJ/mol, is one substance that can be used in cold pack. If the goal is to decrease the te

mperature from 25.0 °C to 5.0 °C, how many grams of NH4NO3 should we use for every 100.0 g of water in the cold pack? Assume no heat was lost outside of cold pack, and the specific heat of the resulted solution was the same as water, or 4.184 J/(g•°C).
Chemistry
1 answer:
makvit [3.9K]3 years ago
6 0

Answer:

There are necessaries 35,2g of NH₄NO₃ per 100,0g of water to decrease the temperature of the solution from 25,0°C to 5,0°C

Explanation:

To decrease the temperature of the solution there are necessaries:

4,184J/g°C×(5,0°C-25,0°C)×(100,0g+X) = -Y

8368J + 83,68J/gX = Y <em>(1)</em>

Where x are grams of NH₄NO₃ you need to add and Y is the energy that you need to decrease the heat.

Also, the energy Y will be:

Y = 25700J/mol×\frac{1mol}{80,043g}X

Y = 321J/g X <em>(2)</em>

Replacing (2) in (1)

8368J + 83,68J/g X = 321J/g X

8363J = 237,32J/gX

<em>X = 35,2g</em>

<em />

Thus, there are necessaries 35,2g of NH₄NO₃ per 100,0g of water to decrease the temperature of the solution from 25,0°C to 5,0°C

I hope it helps!

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4C₃H₅O₂ + 13O₂ → 12CO₂ + 10H₂O

Explanation:

The reaction can be expressed as:

CₓHₓOₓ + nO₂ → CO₂ + H₂O

Under the assumption that there was a total combustion, all of the carbon in the reactant was combusted into CO₂, so <u>the mass of C contained in the C.H.O. compound is the same mass of C contained in 1.039 g of CO₂</u>:

1.039gCO_{2}*\frac{1molCO_{2}}{44gCO_{2}} *\frac{1molC}{1molCO_{2}} *\frac{12gC}{1molC} =0.2834gC

All of the hydrogens atoms in the compound ended up becoming H₂O, so <u>the mass of H contained in the C.H.O. compound is the same mass of H contained in 0.6369 g of H₂O</u>:

0.6369g*\frac{1molH_{2}O}{18gH_{2}O} *\frac{1molH}{1molH_{2}O} *\frac{1gH}{1molH} =0.0354gH

Because the compound is composed only by C, H and O, <u>the mass of O in the compound can be calculated by substraction</u>:

0.5438 g Compound - 0.2834 g C - 0.0354 g H = 0.2250 g O

In order to determine the empirical formula, we calculate the moles of each component:

  • mol C = 0.2834 g C ÷ 12 g/mol = 0.0236 mol C
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  • mol O = 0.2250 g O ÷ 16 g/mol = 0.0141 mol O

Then we divide those values by the lowest one:

0.0236 mol C ÷ 0.0141 = 1.67

0.0354 mol H ÷ 0.0141 = 2.51

0.0141 mol O ÷ 0.0141 = 1

If we multiply those values by 2, we're left with the empirical formula C₃H₅O₂.

  • The reaction is:

4C₃H₅O₂ + 13O₂ → 12CO₂ + 10H₂O

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