Wolff-kishner reduction (hydrazine, koh, ethylene glycol, 130°c) of the compound shown gave compound
1 answer:
The scheme is shown below, the steps involved are as follow,
Step one: Reduction:
The carbonyl group of given compound on reduction using Wolf Kishner reagent converts the carbonyl group into -CH₂- group.
Step two: Epoxidation:
The double bond present in starting compound when treated with m-CPBA (<span>meta-Chloroperoxybenzoic acid) gives corrsponding epoxide.
Step three: Reduction:
The epoxide is reduced to alcohol on treatment with Lithium Aluminium Hydride (LiAlH</span>₄)<span> followed by hydrolysis.
Step four: Oxidation:
The hydroxyl group (alcohol) is oxidized to carbonyl (ketonic group) using oxidizing agent Chromic acid (H</span>₂CrO₄).
Step one: Reduction:
The carbonyl group of given compound on reduction using Wolf Kishner reagent converts the carbonyl group into -CH₂- group.
Step two: Epoxidation:
The double bond present in starting compound when treated with m-CPBA (<span>meta-Chloroperoxybenzoic acid) gives corrsponding epoxide.
Step three: Reduction:
The epoxide is reduced to alcohol on treatment with Lithium Aluminium Hydride (LiAlH</span>₄)<span> followed by hydrolysis.
Step four: Oxidation:
The hydroxyl group (alcohol) is oxidized to carbonyl (ketonic group) using oxidizing agent Chromic acid (H</span>₂CrO₄).
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Answer:
0.185moles
Explanation:
Given parameters:
Volume of O₂ = 49.8L
Unknown:
Number of moles of sucrose required = ?
Solution:
We can assume that the reaction takes place at standard temperature and pressure.
From this, we can find the number of moles of oxygen that reacted and extrapolate to that of sucrose.
Chemical equation;
C₁₂H₂₂0₁₁ + 120₂ → 12CO₂ + 11H₂0
Number moles = at STP
Number of moles of oxygen gas = = 2.22moles
12 moles of oxygen gas combines with 1 mole of sucrose
2.22 moles of oxygen gas will combine with = 0.185moles