Explanation:
Work done by gravity is given by the formula,
W = ......... (1)
It is known that when levels are same then height of the liquid is as follows.
h = ......... (2)
Putting value of equation (2) in equation (1) the overall formula will be as follows.
W =
=
= 0.689 J
Thus, we can conclude that the work done by the gravitational force in equalizing the levels when the two vessels are connected is 0.689 J.
Answer : The change in enthalpy of the reaction is, -310 kJ
According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.
The given main reaction is,
The intermediate balanced chemical reaction will be,
(1)
(2)
(3)
Now we will reverse the reaction 1 and multiply reaction 1 by 2, reaction 2 by 2 and reaction 3 by 3 then adding all the equations, we get :
(1)
(2)
(3)
The expression for enthalpy of formation of will be,
Therefore, the change in enthalpy of the reaction is, -310 kJ