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Slav-nsk [51]
3 years ago
11

Gaseous ethane (CH,CH,) will react with gaseous oxygen (0,) to produce gaseous carbon dioxide (CO) and gaseous water (H2O). Supp

ose 1.50 g of
ethane is mixed with 11. g of oxygen. Calculate the minimum mass of ethane that could be left over by the chemical reaction. Round your answer to 2
significant digits.
​
Chemistry
1 answer:
notka56 [123]3 years ago
8 0

Answer:

0.00 g

Explanation:

We have the masses of two reactants, so this is a limiting reactant problem.  

We will need a balanced equation with masses, moles, and molar masses of the compounds involved.

1. Gather all the information in one place with molar masses above the formulas and masses below them.  

Mᵣ            30.07      32.00  

              2CH₃CH₃ + 7O₂ ⟶ 4CO₂ + 6H₂O

Mass/g:      1.50          11.

2. Calculate the moles of each reactant  

\text{moles of C$_{2}$H}_{6} = \text{1.50 g C$_{2}$H}_{6} \times \dfrac{\text{1 mol C$_{2}$H}_{6}}{\text{30.07 g C$_{2}$H}_{6}} = \text{0.04988 mol C$_{2}$H}_{6}\\\\\text{moles of O}_{2} = \text{11. g O}_{2} \times \dfrac{\text{1 mol O}_{2}}{\text{32.00 g O}_{2}} = \text{0.34 mol O}_{2}

3. Calculate the moles of CO₂ we can obtain from each reactant

From ethane:

The molar ratio is 4 mol CO₂:2 mol C₂H₆

\text{Moles of CO}_{2} = \text{0.04988 mol C$_{2}$H}_{6} \times \dfrac{\text{4 mol CO}_{2}}{\text{2 mol C$_{2}$H}_{6}} = \text{0.09976 mol CO}_{2}

From oxygen:

The molar ratio is 4 mol CO₂:7 mol O₂

\text{Moles of CO}_{2} =  \text{0.34 mol O}_{2}\times \dfrac{\text{4 mol CO}_{2}}{\text{7 mol O}_{2}} = \text{0.20 mol CO}_{2}

4. Identify the limiting and excess reactants

The limiting reactant is ethane, because it gives the smaller amount of CO₂.

The excess reactant is oxygen.

5. Mass of ethane left over.

Ethane is the limiting reactant. It will be completely used up.

The mass of ethane left over will be 0.00 g.

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Answer:

Approximately 81.84\%.

Explanation:

Balanced equation for this reaction:

{\rm Na_{2}CO_{3}}\, (aq) + {\rm CaCl_{2}} \, (aq) \to 2\; {\rm  NaCl}\, (aq) + {\rm CaCO_{3}}\, (s).

Look up the relative atomic mass of elements in the limiting reactant, \rm CaCl_{2}, as well as those in the product of interest, \rm CaCO_{3}:

  • \rm Ca: 40.078.
  • \rm Cl: 35.45.
  • \rm C: 12.011.
  • \rm O: 15.999.

Calculate the formula mass for both the limiting reactant and the product of interest:

\begin{aligned}& M({\rm CaCl_{2}}) \\ &= (40.078 + 2 \times 35.45)\; {\rm g \cdot mol^{-1}} \\ &= 110.978\; \rm g \cdot mol^{-1}\end{aligned}.

\begin{aligned}& M({\rm CaCO_{3}}) \\ &= (40.078 + 12.011 + 3 \times 15.999)\; {\rm g \cdot mol^{-1}} \\ &= 100.086\; \rm g \cdot mol^{-1}\end{aligned}.

Calculate the quantity of the limiting reactant (\rm CaCl_{2}) available to this reaction:

\begin{aligned}n({\rm CaCl_{2}) &= \frac{m({\rm {CaCl_{2}})}}{M({\rm CaCl_{2}})} \\ &= \frac{17.87\; \rm g}{110.978\; \rm g \cdot mol^{-1}} \\ &\approx 0.161023\; \rm mol \end{aligned}.

Refer to the balanced equation for this reaction. The coefficients of the limiting reactant (\rm CaCl_{2}) and the product ({\rm CaCO_{3}}) are both 1. Thus:

\displaystyle \frac{n({\rm CaCO_{3}})}{n({\rm CaCl_{2}})} = 1.

In other words, for every 1\; \rm mol of \rm CaCl_{2} formula units that are consumed, 1\; \rm mol\! of \rm CaCO_{3} formula units would (in theory) be produced. Thus, calculate the theoretical yield of \rm CaCO_{3}\! in this experiment:

\begin{aligned} & n(\text{${\rm CaCO_{3}}$, theoretical}) \\ =\; & n({\rm CaCl_{2}}) \cdot \frac{n({\rm CaCO_{3}})}{n({\rm CaCl_{2}})} \\ \approx \; & 0.161023\; {\rm mol} \times 1 \\ =\; & 0.161023\; \rm mol\end{aligned}.

Calculate the theoretical yield of this experiment in terms of the mass of \rm CaCO_{3} expected to be produced:

\begin{aligned} & m(\text{${\rm CaCO_{3}}$, theoretical}) \\ = \; & n(\text{${\rm CaCO_{3}}$, theoretical}) \cdot M(({\rm CaCO_{3}}) \\ \approx \; & 0.161023\; {\rm mol} \times 100.086\; {\rm g \cdot mol^{-1}} \\ \approx \; & 16.1161\; \rm g \end{aligned}.

Given that the actual yield in this question (in terms of the mass of \rm CaCO_{3}) is 13.19\; \rm g, calculate the percentage yield of this experiment:

\begin{aligned} & \text{percentage yield} \\ =\; & \frac{\text{actual yield}}{\text{theoretical yield}} \times 100\% \\ \approx \; & \frac{13.19\; {\rm g}}{16.1161\; {\rm g}} \times 100\% \\ \approx \; & 81.84\%\end{aligned}.

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