Answer :
<em>(b) 4d orbitals would be larger in size than 3d orbitals</em>
<em>(e) 4d orbitals would have more nodes than 3d orbitals</em>
Explanation :
As we move away from one orbital to another, the distance between nucleus and orbital increases. So, 4d orbitals would be far to the nucleus than 3d orbitals.
Hence, 4d orbitals would be larger in size than 3d orbitals.
Number of nodes is any orbital is n - 1 where, n is principal quantum number.
So, number of orbital in 4d is 3.
And number of orbital in 3d is 2.
So, options (b) and (e) are correct.