Answer:
b. The splitting of the d-orbitals is smaller in the [Ni(Cl)6]4- complex than in the [Ni(en)3]2+ complex.
Explanation:
The spectrochemical series is an arrangement of ligands in increasing order of their magnitude of crystal field splitting.
Ligands that occurs towards the right in the series are called strong field ligands and they tend to cause a greater magnitude of crystal field splitting. Ligands that occur towards the left hand side in the series are called weak field ligands and they tend to cause a lesser magnitude of crystal field splitting.
Since Cl^- is a weak field ligand, it causes a lesser magnitude of d orbital splitting compared to ethylenediammine (en) which causes a greater magnitude of d orbital splitting.
Hence; the splitting of the d-orbitals is smaller in the [Ni(Cl)6]4- complex than in the [Ni(en)3]2+ complex.
Answer:
Magnesium chloride and water
Explanation:
Mg(OH)₂ + 2HCl ⟶ MgCl₂ + 2H₂O
magnesium chloride water
Answer: -64.1 kJ.
Explanation:
According to first law of thermodynamics:
=Change in internal energy
q = heat absorbed or released
w = work done or by the system
w = work done by the system=
{Work is done by the system is negative as the final volume is greater than initial volume}
w = -855 Joules = 0.855 kJ (1kJ=1000J)
q = -65.0 kJ {Heat released by the system is negative}
Thus the change internal energy (ΔE) for a system that is giving off 65.0 kJ of heat and is performing 855 J of work on the surroundings is -64.1 kJ.
Answer is: mass of silver chloride is 34,82 g.
Chemical
reaction: AgNO₃ +
NaCl → AgCl + NaNO₃.
<span>m(AgNO</span>₃) = 53,42 g..<span>
m(NaCl) = 14,19 g.
n(AgNO</span>₃) = m(AgNO₃) ÷ M(AgNO₃).<span>
n(AgNO</span>₃) = 53,42 g ÷ 169,87 g/mol.
n(AgNO₃) = 0,314 mol.
n(NaCl) = 14,19 g ÷ 58,4 g/mol.
n(NaCl) = 0,242 mol; limiting reactant.
From chemical reaction: n(NaCl) : n(AgCl) = 1 : 1.<span>
n</span>(AgCl)<span> = 0,242 mol.
m</span>(AgCl) = 0,252 mol · 143,32 g/mol.
m(AgCl) = 34,82 g.
