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QveST [7]
3 years ago
11

A sample of carbon dioxide occupies a volume of 1.50L at 165KPå pressure. What pressure would the gas exert if the volume was in

creased to
2.5L?

a.0.023 kPa
b. 275 kPa
c. 99 L
d. 99 kPa​
Chemistry
1 answer:
Sholpan [36]3 years ago
4 0

Answer:

B. 275 kPa

Explanation:

Since we need to find the greater value, because 1.50<2.5, then the only greater value would be 275 kPa.

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Answer : The values of \Delta H^o,\Delta S^o\text{ and }\Delta G^o are 33.89kJ,95.94J/K\text{ and }5.299kJ/mol respectively.

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\Delta H^o=H_f_{product}-H_f_{reactant}

\Delta H^o=[n_{C_6H_6(g)}\times \Delta H_f^0_{(C_6H_6(g))}]-[n_{C_6H_6(l)}\times \Delta H_f^0_{(C_6H_6(l))}]

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\Delta H_f^0_{(C_6H_6(l))} = standard enthalpy of formation  of liquid benzene = 49.04 kJ/mol

Now put all the given values in this expression, we get:

\Delta H^o=[1mole\times (82.93kJ/mol)]-[1mole\times (49.04J/mol)]

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Now we have to calculate the entropy of reaction (\Delta S^o).

\Delta S^o=S_f_{product}-S_f_{reactant}

\Delta S^o=[n_{C_6H_6(g)}\times \Delta S^0_{(C_6H_6(g))}]-[n_{C_6H_6(l)}\times \Delta S^0_{(C_6H_6(l))}]

where,

\Delta S^o = entropy of reaction = ?

n = number of moles

\Delta S^0_{(C_6H_6(g))} = standard entropy of formation  of gaseous benzene = 269.2 J/K.mol

\Delta S^0_{(C_6H_6(l))} = standard entropy of formation  of liquid benzene = 173.26 J/K.mol

Now put all the given values in this expression, we get:

\Delta S^o=[1mole\times (269.2J/K.mol)]-[1mole\times (173.26J/K.mol)]

\Delta S^o=95.94J/K.mol

Now we have to calculate the Gibbs free energy of reaction (\Delta G^o).

As we know that,

\Delta G^o=\Delta H^o-T\Delta S^o

At room temperature, the temperature is 25^oC\text{ or }298K.

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\Delta G^o=5299.88J/mol=5.299kJ/mol

Therefore, the values of \Delta H^o,\Delta S^o\text{ and }\Delta G^o are 33.89kJ,95.94J/K\text{ and }5.299kJ/mol respectively.

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