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Zepler [3.9K]
4 years ago
15

A protein has the amino acid sequence

Chemistry
1 answer:
kherson [118]4 years ago
6 0

Answer:

Number of peptide fragments resulting from cleaving with cyanogen bromide? A: Three peptide fragments

Number of peptide fragments resulting from cleaving with trypsin? A: Four peptide fragments

Which of these reagents gives the smallest single fragment (in number of amino acid residues)? A: CnBr, a dipeptide fragment consisting of AL (Alanine-Leucine)

Explanation:

Cyanogen bromide cleaves the methionine C-terminus, then we have a first fragment of 8 amino acids: DSRLSKTM, a second fragment of 15 aas YSIEAPAKLDWEQNM, and a last fragment of only 2 aas is produced, AL

Trypsin cuts the C-terminus of Arginine and Lysine, then we'll have a first fragment of 3 aas DSR, a second fragment consisting of also 3 aas LSK, a third fragment of 10 aas TMYSIEAPAK, and a last fragment of 9 aas LDWEQNMAL.  All produced in three cut sites.

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For the equilibrium PCl5(g) PCl3(g) + Cl2(g), Kc = 2.0 × 101 at 240°C. If pure PCl5 is placed in a 1.00-L container and allowed
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the equilibrium concentration of [PCl₅] is 3.64*10⁻³ M

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and [A] denote concentrations of A

if initially the mixture is pure PCl₅ , then it will dissociate according to the reaction and since always one mole of PCl₃(g) is generated with one mole of Cl₂(g) , the total number of moles of both at the end is the same → they have the same concentration → [PCl₃(g)] = [Cl₂]=0.27 M

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[PCl₅]  = 3.64*10⁻³ M

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