Answer:
M = 16.8 M
Explanation:
<u>Data:</u> HNO3
moles = 12.6 moles
solution volume = 0.75 L
Molarity is represented by the letter M and is defined as the amount of solute expressed in moles per liter of solution.
The data is replaced in the given equation:
Explanation:
According to the Beer-lambert' s law,
Absrobance = absrobptitvity × lenght × concentration
So, if we will plot a graph between absrobance and concentration then we will obtain a straight line
Hence, formula to calculate slope of the graph is as follows.
The slope of graph =
The given data is as follows.
= 0.412 (first point)
= 0.642 (second point)
= 0.240 ppm (first point)
= 0.475 ppm (second point)
Hence, putting these values into the above formula we will calculate the value of slope as follows.
Slope =
=
=
= 0.978
It is known that for the graph, line equation can be written as follows.
y = mx + c ........... (1)
where, C = intercept
m = slope
Hence, calculate the value of intercept as follows.
0.412 = + c
c = 0.178
As it is given that the absorbance values 0.454 (the y-axis value). Therefore, putting this value into equation (1) we get the following.
y = mx + c
0.454 = + 0.178
0.276 = 0.978x
x = 0.282 ppm
Thus, we can conclude that the concentration of Pb in the given sample is 0.282 ppm.
Step 1 : Write balanced chemical equation
The balanced chemical equation for the reaction between iodine gas and chlorine gas is given below.
Step 2 : Set up ICE table
We will set up an ICE table for the above reaction
Following points are considered while drawing ICE table
- The initial concentration of product is assumed as 0
- The change in concentration (C) is assumed as x. Change (x) is negative for reactants and positive for products
- The coefficients in balanced equation are considered while writing C values
Check attached file for ICE table
Step 3 : Set up equilibrium constant equation
The equation for equilibrium constant can be written as
Step 4 : Solving for x
Keq at 298.15 K is given as 81.9
Let us plug in the equilibrium values (E) for I₂, Cl₂ and ICl from ICE table
81.9 =
81.9 =
Solving the above equation using quadratic formula we get
x = 0.488 or x = 0.254
The value 0.488 cannot be used because the change (C) cannot be greater that initial concentration of the reactants.
Therefore the change in concentration of the gases during the reaction is 0.254 M
Hence, x = 0.254 M
From the ICE table, we know that the equilibrium concentration of ICl is 2x
The concentration of ICl when the reaction reaches equilibrium is 0.508 M
