When bonds between atoms are broken or formed, what is the outcome?
2 answers:
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Mixing of pure orbitals having nearly equal energy to form equal number of completely new orbitals is said to be hybridization.
For the compound, the electronic configuration of the atoms, carbon and hydrogen are:
Carbon (atomic number=6): In ground state=
In excited state:
Hydrogen (atomic number=1):
All the bonds in the compound is single bond(-bond) that is they are formed by head on collision of the orbitals.
The structure of the compound is shown in the image.
The Carbon-Hydrogen bond is formed by overlapping of s-orbital of hydrogen to p-orbital of carbon.
In order to complete the octet the required number of electrons for carbon is 4 and for hydrogen is 1. So, the electron in of hydrogen will overlap to the 2p^{3}-orbital of carbon.
Thus, the hybridization of Hydrogen is -hybridization and the hybridization of Carbon is
-hybridization.
The hybridization of each atom is shown in the image.
Answer: The last electron will be filled in first orbital of 3p sub-shell.
Explanation: Filling of electrons in orbitals is done by using Hund's Rule.
Hund's rule states that the electron will be singly occupied in the orbital of the sub-shell before any orbital is doubly occupied.
For filling up of the electrons in Sulfur atom having 16 electrons. First 10 electrons will completely fill according to Aufbau's Rule in 1s, 2s and 2p sub-shells and last 6 electrons are the valence electrons which will be filled in the order of 3s and then 3p.
3s sub-shell will be fully filled and the orbitals of 3p sub-shell will be first singly occupied and then pairing will take place. Hence, the last electron will be filled in the first orbital of 3p-sub-shell.
