Answer:
Overall reaction equation;
2NO(g) +Cl2(g) -----> 2NOCl (g)
Explanation:
Given
1) NO(g) + Cl2(g) → NOCl2(g)
2) NOCl2(g) + NO(g) → 2NOCl(g)
Overall reaction equation;
2NO(g) +Cl2(g) -----> 2NOCl (g)
k1= [NOCl2]
k-1= [NO] [Cl2]
k2 = [NOCl2] [NO]
Equilibrium for the first equation (reaction 1)
K= k1/k-1 = [NOCl2]/[NO] [Cl2]
Therefore
[NOCl2] = k1/k-1 [NO] [Cl2]
Rate= k2× k1/k-1 [NO]^2 [Cl2]
Rate = Koverall [NO]^2 [Cl2]
Where Koverall= k1k2/k-1
Answer:
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Explanation:
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Answer:
q = 40.57 kJ; w = -3.10 kJ; strong H-bonds must be broken.
Explanation:
1. Heat absorbed
q = nΔH = 1 mol × (40.57 kJ/1 mol) = 40.57 kJ
2. Change in volume
V(water) = 0.018 L
pV = nRT
1 atm × V = 1 mol × 0.082 06 L·atm·K⁻¹mol⁻¹ × 373.15 K
V = 30.62 L
ΔV = V(steam) - V(water) = 30.62 L - 0.018 L = 30.60 L
3. Work done
w = -pΔV = - 1 atm × 30.60 L = -30.60 L·atm
w = -30.60 L·atm × (101.325 J/1 L·atm) = -3100 J = -3.10 kJ
4. Why the difference?
Every gas does 3.10 kJ of work when it expands at 100 °C and 1 atm.
The difference is in the heat of vaporization. Water molecules are strongly hydrogen bonded to each other, so it takes a large amount of energy to convert water from the liquid phase to the vapour phase.
The answer is C. <span>The density of the fluid is greater than the density of the object.</span>
