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The equilibrium constant Kp for the reaction (CH3),CCI (g) = (CH3),C=CH, (g) + HCl (g) is 3.45 at 500. K. (5.00 x 10K) Calculate

Karolina [17]

<u>Answer:</u> The value of $K_p$ for the reaction is 6.32 and concentrations of $(CH_3)_2C=CH,HCl\text{ and }(CH_3)_3CCl$ is 0.094 M, 0.094 M and 0.106 M respectively.

<u>Explanation:</u>

Relation of $K_p$ with $K_c$ is given by the formula:

$K_p=K_c(RT)^{\Delta ng}$

where,

$K_p$ = equilibrium constant in terms of partial pressure = 3.45

$K_c$ = equilibrium constant in terms of concentration = ?

R = Gas constant = $0.0821\text{ L atm }mol^{-1}K^{-1}$

T = temperature = 500 K

$\Delta n_g$ = change in number of moles of gas particles = $n_{products}-n_{reactants}=2-1=1$

Putting values in above equation, we get:

$3.45=K_c\times (0.0821\times 500)^{1}\\\\K_c=\frac{3.45}{0.0821\times 500}=0.084$

The equation used to calculate concentration of a solution is:

$\text{Molarity}=\frac{\text{Moles}}{\text{Volume (in L)}}$

Initial moles of $(CH_3)_3CCl(g)$ = 1.00 mol

Volume of the flask = 5.00 L

So, $\text{Concentration of }(CH_3)_3CCl=\frac{1.00mol}{5.00L}=0.2M$

For the given chemical reaction:

$(CH_3)_3CCl(g)\rightarrow (CH_3)_2C=CH(g)+HCl(g)$

Initial: 0.2 - -

At Eqllm: 0.2 - x x x

The expression of $K_c$ for above reaction follows:

$K_c=\frac{[(CH_3)_2C=CH]\times [HCl]}{[(CH_3)_3CCl]}$

Putting values in above equation, we get:

$0.084=\frac{x\times x}{0.2-x}\\\\x^2+0.084x-0.0168=0\\\\x=0.094,-0.178$

Negative value of 'x' is neglected because initial concentration cannot be more than the given concentration

Calculating the concentration of reactants and products:

$[(CH_3)_2C=CH]=x=0.094M$

$[HCl]=x=0.094M$

$[(CH_3)_3CCl]=(0.2-x)=(0.2-0.094)=0.106M$

Hence, the value of $K_p$ for the reaction is 6.32 and concentrations of $(CH_3)_2C=CH,HCl\text{ and }(CH_3)_3CCl$ is 0.094 M, 0.094 M and 0.106 M respectively.

8 0

3 years ago

How do you test for starch in green plant

Sunny_sXe [5.5K]

Answer:

1,Iodine solution is used to test leaves for the presence of starch. ...

2.After a few minutes, the parts of the leaf that contain starch turn the iodine from brown to blue/black.

3.The leaf on the left is a variegated leaf

Explanation:

4 0

3 years ago

Read 2 more answers

Difference betwifference between a mixture or compound

Hatshy [7]

The difference between a mixture and a compound is that a mixture can be easily separated like a salad where you can pick things out and a compounds you are usually not able to undo

7 0

3 years ago

Why does determining volume work only for a regular shaped object

Kitty [74]

Answer:

Because only regular-shaped objects have a consistent length, width, height, and shape.

Explanation:

Because only regular-shaped objects have a consistent length, width, height, and shape. When dealing with an object composed of differing shapes, your must calculate each portion separately and then add them.

5 0

3 years ago

The reactants of two chemical equations are listed. Equation 1: PbNO3 + Mg Equation 2: PbNO3 + KI Based on the type of reaction,

Vika [28.1K]

Answer:

Equation 2, because K being more reactive, exchanges position with Pb in PbNO3.

Explanation:

Hello there!

In this case, according to the given reactions, it is possible to realize that according to the reactivity series, since K is is group 1A of alkali metals, we infer it is by far more reactive than magnesium, for that reason last two choices can be easily discarded. Now, considering equation 2, it would be necessary to complete it to figure out the correct option:

$Pb(NO_3)_2 + KI \rightarrow PbI_2+KNO_3$

Whereas it can be seen that potassium exchanges position with Pb according to the double displacement reaction; therefore, the correct answer is "Equation 2, because K being more reactive, exchanges position with Pb in PbNO3".

Best regards!

8 0

3 years ago

What is one Scientific Law or Scientific Theory that affects our life?​

What is one Scientific Law or Scientific Theory that affects our life?