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crimeas [40]
3 years ago
14

The decomposition of AB given here in this balanced equation 2AB (g)⟶ A2 (g) + B2 (g), has rate constants of 8.58 x 10-9 L/mol s

at 325°C and 2.16 x 10-5 L/mol x at 407°C. Find the activation energy
Chemistry
1 answer:
denis-greek [22]3 years ago
8 0

Answer:

3.24 × 10^5 J/mol

Explanation:

The activation energy of this reaction can be calculated using the equation:

ln(k2/k1) = Ea/R x (1/T1 - 1/T2)

Where; Ea = the activation energy (J/mol)

R = the ideal gas constant = 8.3145 J/Kmol

T1 and T2 = absolute temperatures (K)

k1 and k2 = the reaction rate constants at respective temperature

First, we need to convert the temperatures in °C to K

T(K) = T(°C) + 273.15

T1 = 325°C + 273.15

T1 = 598.15K

T2 = 407°C + 273.15

T2 = 680.15K

Since, k1= 8.58 x 10-9 L/mol, k2= 2.16 x 10-5 L/mol, R= 8.3145 J/Kmol, we can now find Ea

ln(k2/k1) = Ea/R x (1/T1 - 1/T2)

ln(2.16 x 10-5/8.58 x 10-9) = Ea/8.3145 × (1/598.15 - 1/680.15)

ln(2517.4) = Ea/8.3145 × 2.01 × 10^-4

7.831 = Ea(2.417 × 10^-5)

Ea = 3.24 × 10^5 J/mol

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4 years ago
The main criterion for sigma bond formation is that the two bonded atoms have valence orbitals with lobes that point directly at
nalin [4]

Answer:

The given statement - The main criterion for sigma bond formation is that the two bonded atoms have valence orbitals with lobes that point directly at each other along the line between the two nuclei , is <u>True.</u>

Explanation:

The above statement is correct , because the sigma bond is produced by the head on overlapping, the orbitals should all point in the same direction.

<u>SIGMA BONDS -</u> Sigma bonds (bonds) are the strongest type of covalent chemical bond in chemistry. They're made up of atomic orbitals that collide head-on. For diatomic molecules, sigma bonding is best characterized using the language and tools of symmetry groups.

Head-on overlapping of atomic orbitals produces sigma bonds. The concept of sigma bonding is expanded to include bonding interactions where a single lobe of one orbital overlaps with a single lobe of another. Propane, for example, is made up of ten sigma bonds, one for each of the two CC bonds and one for each of the eight CH bonds.

Hence , the answer is true .

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4 years ago
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Given 20.0 g of (NH4)3 PO3 how many moles is this? How many formula units is it? How many hydrogen atoms are present?
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Answer:

no of moles = (mass) ÷ molar mass

you get the molar mass from the periodic table

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