Parts per million is one way of expressing concentration. Usually, it is used in describing a solute in water. One parts per million or one ppm is equal to 1 milligram of solute per liter of solution or 1 milligram of solute per kg solution. Thus, the total mass of the solute is 0.005 g.
The Law of Definite proportions states that a given chemical compound always contains its component elements in fixed ratio (by mass) and does not depend on its source and method of preparation.