Answer:
The group reagent is H2S in the presence of NH4Cl .
Explanation:
Mn is fourth group radical in qualitative analysis ;
the group reagent is H2S in the presence of NH4Cl .
then Mn precipitates as buff coloured sulphide , which is soluble in HCl .
MnS + 2HCl ---------> MnCl2 + H2S
on heating the solution with NaOH with bromine water, manganesedioxide gets precipitated.
MnCl2 + 2NaOH --------> Mn(OH)2 + 2NaCl
Mn(OH)2 + O -------> MnO2 + H2O
whereas NiS is insoluble in HCl. the nickel chloride gives a scarlet red precipitate with dimethy gly oxime.
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Answer: The osmotic pressure of 5.0g of sucrose solution in 1 L is 271.32 torr.
Explanation:
Given: Mass = 5.0 g
Volume = 1 L
Molar mass of sucrose = 342.3 g/mol
Moles are the mass of a substance divided by its molar mass. So, moles of sucrose are calculated as follows.

Hence, concentration of sucrose is calculated as follows.

Formula used to calculate osmotic pressure is as follows.

where,
= osmotic pressure
C = concentration
R = gas constant = 0.0821 L atm/mol K
T = temperature
Substitute the values into above formula as follows.

Thus, we can conclude that the osmotic pressure of 5.0g of sucrose solution in 1 L is 271.32 torr.
I think its, A because its below the lithosphere and the lithosphere it between the crust and mantel. no liquids there.