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vladimir2022 [97]
3 years ago
15

If the activation energy for a given compound is found to be 42.0 kJ/mol, with a frequency factor of 8.0 × 1010 s-1, what is the

rate constant for this reaction at 298 K?
Chemistry
1 answer:
Sveta_85 [38]3 years ago
8 0

Answer:3480s⁻¹

Explanation:We can solve the following problem using the Arrhenius equation.

Arrhenius equation is given by:

K=Aexp[-Ea/RT]

A=Pre-exponential factor or frequency factor

Ea=Activation energy

R=Ideal gas constant

T=Temperature

K=Rate constant

From the Arrhenius equation we can see that  the rate constant K is related with the activation energy and frequency factor.

In the question we are given with the following data:

Ea=42KJ/mol=42x 1000 J/mol

A=8.0×10¹ per second

T=298K

R=8.314J/K mol

when we substitute these given values in Arrhenius equation

K=A{exp[-Ea \div RT]}\\K=8\ \times10^{10} s^{-1}{exp[-42000\div 8.314\times298]}\\K=8\ \times10^{10} s^{-1}{exp[-16.95]}\\K=4.35\times10^{^{-8}}\times8.0\times10^{^{10}}s^{-1}\\K=34.8\times10^{2}s^{-1}\\

K=3480s⁻¹

The value of rate constant obtained is 3480s⁻¹.

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Answer:

a. i. 8.447 × 10⁻³ T ii.  27.14 cm

b. i. 2.14 cm ii. It is easily detectable.

Explanation:

a.

i. What strength of magnetic field is required?

Since the magnetic force F = Bqv equals the centripetal force F' = mv²/r on the C12 charge, we have

F = F'

Bqv = mv²/r

B = mv/re where B = strength of magnetic field, m = mass of C12 isotope = 1.99 × 10⁻²⁶ kg, v = speed of C 12 isotope = 8.50 km/s = 8.50 × 10³ m/s, q = charge on C 12 isotope = e = electron charge = 1.602 × 10⁻¹⁹ C (since the isotope loses one electron)and r = radius of semicircle = 25.0 cm/2 = 12.5 cm = 12.5 × 10⁻² m

So,

B = mv/rq

B = 1.99 × 10⁻²⁶ kg × 8.50 × 10³ m/s ÷ (12.5 × 10⁻² m × 1.602 × 10⁻¹⁹ C)

B = 16.915 × 10⁻²³ kgm/s ÷ (20.025 × 10⁻²¹ mC)

B = 0.8447 × 10⁻² kg/sC)

B = 8.447 × 10⁻³ T

(ii) What is the diameter of the 13C semicircle?

Since the magnetic force F = Bq'v equals the centripetal force F' = mv²/r' on the C13 charge, we have

F = F'

Bq'v = mv²/r'

r' = mv/Be where r = radius of semicircle, B = strength of magnetic field = 8.447 × 10⁻³ T, m = mass of C12 isotope = 2.16 × 10⁻²⁶ kg, v = speed of C 12 isotope = 8.50 km/s = 8.50 × 10³ m/s, q' = charge on C 13 isotope = e = electron charge = 1.602 × 10⁻¹⁹ C (since the isotope loses one electron) and  = d/2 = 12.5 cm = 12.5 × 10⁻² m

So, r' = mv/Be

r' = 2.16 × 10⁻²⁶ kg × 8.50 × 10³ m/s ÷ (8.447 × 10⁻³ T × 1.602 × 10⁻¹⁹ C)

r' = 18.36 × 10⁻²³ kgm/s ÷ 13.5321 × 10⁻²² TC)

r' = 1.357 × 10⁻¹ kgm/TC)

r' = 0.1357 m

r' = 13.57 cm

Since diameter d' = 2r', d' = 2(13.57 cm) = 27.14 cm

b.

i. What is the separation of the C12 and C13 ions at the detector at the end of the semicircle?

Since the diameter of the C12 isotope is 25.0 cm and that of the C 13 isotope is 27.14 cm, their separation at the end of the semicircle is 27.14 cm - 25.0 cm = 2.14 cm

ii. Is this distance large enough to be easily observed?

This distance of 2.14 cm easily detectable since it is in the centimeter range.

7 0
2 years ago
PLEASE HELP
anastassius [24]

Answer:

B??? sorry if im wrong

Explanation:

7 0
3 years ago
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What intermolecular force(s) is/are present in solid SO3?
guapka [62]

Answer:

1. London dispersion

Explanation:

Sulphur trioxide ( SO₃ ) -

The chemical compound SO₃ is planar in structure , the only intermolecular forces shown by SO₃ is the London forces .

dipole - dipole is not observed in this compound , as it is not possible to generate poles between the sulfur and oxygen atom due to very less difference in the electronegativity .

Hydrogen bonding is also not observed , because there is not hydrogen atom .

Hence , only London forces are observed in SO₃ .

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3 years ago
A preliminary untested explanation that tries to explain how or why things happen in the manner observed is a scientific
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It is a scientific hypothesis. A scientific hypothesis must be testable, however there is a significantly more grounded necessity that a testable speculation must meet before it can truly be viewed as logical. This foundation comes essentially from crafted by the rationalist of science Karl Popper, and is called "falsifiability".
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Phosgene, a poisonous gas, when heated will decompose into carbon monoxide and chlorine in a reversible reaction: COCl2 (g) <
Advocard [28]

Answer:

8.08 × 10⁻⁴

Explanation:

Let's consider the following reaction.

COCl₂(g) ⇄ CO (g) + Cl₂(g)

The initial concentration of phosgene is:

M = 2.00 mol / 1.00 L = 2.00 M

We can find the final concentrations using an ICE chart.

     COCl₂(g) ⇄ CO (g) + Cl₂(g)

I       2.00            0            0

C        -x             +x           +x

E    2.00 -x          x             x

The equilibrium concentration of Cl₂, x, is 0.0398 mol / 1.00 L = 0.0398 M.

The concentrations at equilibrium are:

[COCl₂] = 2.00 -x = 1.96 M

[CO] = [Cl₂] = 0.0398 M

The equilibrium constant (Keq) is:

Keq = [CO].[Cl₂]/[COCl₂]

Keq = (0.0398)²/1.96

Keq = 8.08 × 10⁻⁴

4 0
3 years ago
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