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valentinak56 [21]

3 years ago

13

how does the energy required to sublime a substance compare to the energy required to melt the substance

1 answer:

Darya [45]3 years ago

3 0

The energy required to sublime (solid to gas) a substance at 1 ATM pressure is greater than the energy required to melt (solid to liquid) a substance. When you compare the energies in varying pressures, however, this trend is not always the case.

<span>any 'general phase diagram', you can see that under the triple point, when all phases are in equilibrium, have solid and gas meeting under a certain pressure. In a vacuum, it would require less energy to sublime than to melt.</span>

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Gold has density of 19.3 g/cm3; how many grams of gold are in a 16.0 cm3 gold bar?

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An equilibrium mixture of PCl5(g), PCl3(g), and Cl2(g) has partial pressures of 217.0 Torr, 13.2 Torr, and 13.2 Torr, respective

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Answer:

The new partial pressures after equilibrium is reestablished:

$PCl_3,p_1'=6.798 Torr$

$Cl_2,p_2'=26.398 Torr$

$PCl_5,p_3'=223.402 Torr$

Explanation:

$PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)$

At equilibrium before adding chlorine gas:

Partial pressure of the $PCl_3=p_1=13.2 Torr$

Partial pressure of the $Cl_2=p_2=13.2 Torr$

Partial pressure of the $PCl_5=p_3=217.0 Torr$

The expression of an equilibrium constant is given by :

$K_p=\frac{p_1}{p_1\times p_2}$

$=\frac{217.0 Torr}{13.2 Torr\times 13.2 Torr}=1.245$

At equilibrium after adding chlorine gas:

Partial pressure of the $PCl_3=p_1'=13.2 Torr$

Partial pressure of the $Cl_2=p_2'=?$

Partial pressure of the $PCl_5=p_3'=217.0 Torr$

Total pressure of the system = P = 263.0 Torr

$P=p_1'+p_2'+p_3'$

$263.0Torr=13.2 Torr+p_2'+217.0 Torr$

$p_2'=32.8 Torr$

$PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)$

At initail

(13.2) Torr (32.8) Torr (13.2) Torr

At equilbriumm

(13.2-x) Torr (32.8-x) Torr (217.0+x) Torr

$K_p=\frac{p_3'}{p_1'\times p_2'}$

$1.245=\frac{(217.0+x)}{(13.2-x)(32.8-x)}$

Solving for x;

x = 6.402 Torr

The new partial pressures after equilibrium is reestablished:

$p_1'=(13.2-x) Torr=(13.2-6.402) Torr=6.798 Torr$

$p_2'=(32.8-x) Torr=(32.8-6.402) Torr=26.398 Torr$

$p_3'=(217.0+x) Torr=(217+6.402) Torr=223.402 Torr$

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