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kondor19780726 [428]
3 years ago
10

328. mL of 0.00345 M NaI (aq) is combined with 703. mL of 0.00802 M Pb(NO3)2 (aq). Determine if a precipitate will form given th

at the Ksp of Pbl2 is 1.40x10-8.
Chemistry
1 answer:
Vsevolod [243]3 years ago
6 0

Answer:

The solution will not form a precipitate.

Explanation:

The Ksp of PbI₂ is:

PbI₂(s) ⇄ 2I⁻(aq) + Pb²⁺(aq)

Ksp = 1.40x10⁻⁸ = [I⁻]²[Pb²⁺] <em>Concentrations in equilibrium</em>

When 328mL of 0.00345M NaI(aq) is combined with 703mL of 0.00802M Pb(NO₃)₂. Molar concentration of I⁻ and Pb²⁺ are:

[I⁻] = 0.00345M × (328mL / (328mL+703mL) =<em> 1.098x10⁻³M</em>

[Pb²⁺] = 0.00802M × (703mL / (328mL+703mL) =<em> 5.469x10⁻³M</em>

<em />

Q = [I⁻]²[Pb²⁺] <em>Concentrations not necessary in equilibrium</em>

If Q = Ksp, the solution is saturated, Q > Ksp, the solution will form a precipitate, if Q < Ksp, the solution is not saturated.

Replacing:

Q = [1.098x10⁻³M]²[5.469x10⁻³M] = 6.59x10⁻⁹

As Q < Ksp, the solution is not saturated and <em>will not form a precipitate</em>.

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Answer:

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Explanation:

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This is a double displacement or double replacement reaction. The reacting species exchange their partners. We can see here that both the sodium ion and chromium II ion both exchanged partners and picked up each others partners in the product.

Sodium ions and nitrate ions now remain in the solution while chromium II hydroxide which is insoluble is precipitated out of the solution as a solid hence the answer.

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3 years ago
Aclosed system contains an equimolar mixture of n-pentane and isopentane. Suppose the system is initially all liquid at 120°C an
garri49 [273]

Explanation:

The given data is as follows.

      T = 120^{o}C = (120 + 273.15)K = 393.15 K,  

As it is given that it is an equimolar mixture of n-pentane and isopentane.

So,            x_{1} = 0.5   and   x_{2} = 0.5

According to the Antoine data, vapor pressure of two components at 393.15 K is as follows.

               p^{sat}_{1} (393.15 K) = 9.2 bar

               p^{sat}_{1} (393.15 K) = 10.5 bar

Hence, we will calculate the partial pressure of each component as follows.

                 p_{1} = x_{1} \times p^{sat}_{1}

                            = 0.5 \times 9.2 bar

                             = 4.6 bar

and,           p_{2} = x_{2} \times p^{sat}_{2}

                         = 0.5 \times 10.5 bar

                         = 5.25 bar

Therefore, the bubble pressure will be as follows.

                           P = p_{1} + p_{2}            

                              = 4.6 bar + 5.25 bar

                              = 9.85 bar

Now, we will calculate the vapor composition as follows.

                      y_{1} = \frac{p_{1}}{p}

                                = \frac{4.6}{9.85}

                                = 0.467

and,                y_{2} = \frac{p_{2}}{p}

                                = \frac{5.25}{9.85}

                                = 0.527  

Calculate the dew point as follows.

                     y_{1} = 0.5,      y_{2} = 0.5  

          \frac{1}{P} = \sum \frac{y_{1}}{p^{sat}_{1}}

           \frac{1}{P} = \frac{0.5}{9.2} + \frac{0.5}{10.2}

             \frac{1}{P} = 0.101966 bar^{-1}              

                             P = 9.807

Composition of the liquid phase is x_{i} and its formula is as follows.

                   x_{i} = \frac{y_{i} \times P}{p^{sat}_{1}}

                               = \frac{0.5 \times 9.807}{9.2}

                               = 0.5329

                    x_{z} = \frac{y_{i} \times P}{p^{sat}_{1}}

                               = \frac{0.5 \times 9.807}{10.5}

                               = 0.467

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How many electrons in an atom can share the quantum numbers n = 4 and l = 3?
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Answer:

\boxed{\text{14}}

Explanation:

If l = 3, the electrons are in an f subshell.

The number of orbitals with a quantum number l is 2l + 1, so there

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Each orbital can hold two electrons, so the f subshell can hold 14 electrons.

\boxed{\textbf{14 electrons}} \text{ can share the quantum numbers n = 4 and l = 3.}

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4 years ago
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Answer:

Distance = 200 km

Distance = 204 km

Speed = 77 km/h

Time = 21.42 h

Explanation:

Given:

A.

Speed = 100 km/h , Time = 2 h

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B.

Speed = 68 km/h , Time = 3 h

Find:

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C.

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A.

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B.

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C.

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Speed = 77 km/h

D.

Time = 1500 / 70

Time = 21.42 h

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