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3 years ago

12

If the equation, C2H5OH (l) + 3O2 (g) → 2CO2 (g) + 3H2 (l), were performed in a laboratory at room temperature, both of the gas

volumes:
would depend on the surrounding temperature and pressure conditions

must always be equal because the molar ratios are the same

must always be equal because the number of representative particles is the same in the equation

could be calculated without regard to the temperature and pressure surrounding them

1 answer:

JulsSmile [24]3 years ago

3 0

Yes it could be calculated everything that has numbers like those you calculate them and see what u get

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3 years ago

Read 2 more answers

Differences and similarities between liquid and gas

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5 0

4 years ago

If a gas occupies 1532.7 mL at standard temperature, what volume does it occupy at 49.4 ºC if the pressure remains constant?

ElenaW [278]

Answer:

a. 1810mL

Explanation:

When conditions for a gas change under constant pressure (and the number of molecules doesn't change), it follows Charles' Law:

$\dfrac{V_1}{T_1}=\dfrac{V_2}{T_2}$ where the temperatures must be measured in Kelvin

To convert from Celsius to Kelvin, add 273, or use the equation: $T_C+273=T_K$

For this problem, one must also recall that standard temperature is 0°C (or 273K).

So, $T_1 = 273[K]$ , and $T_2 = (49.4+273)[K]=322.4[K]$ .

$\dfrac{V_1}{T_1}=\dfrac{V_2}{T_2}$

$\dfrac{(1532.7[mL])}{(273[K])}=\dfrac{V_2}{(322.4[K])}$

$\dfrac{(1532.7[mL])}{(273[K\!\!\!\!\!{-}])}(322.4[K\!\!\!\!\!{-}] )=\dfrac{V_2}{(322.4[K]\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!{----})}(322.4[K]\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!{----})$

$1810.04571428[mL]=V_2$

Adjusting for significant figures, this gives $V_2=1810[mL]$

4 0

2 years ago

It is proposed to use Liquid Petroleum Gas (LPG) to fuel spark-ignition engines. A typical sample of the fuel on a volume basis

Norma-Jean [14]

Answer:

a)

The overall balanced combustion reaction is written as :

$0.7C_3H_8 \ + \ 0.05C_4H_{10} \ + \ 0.25 C_3H_6 \ + \ x(O_2 \ + \ 3.76N_2) ---> 3.05CO_2 \ + \ 3.8H_2O \ + \ 18.612N_2$

$(F/A)_{stoichiometric} = 0.0424$

$(A/F)_{stoichiometric} = 23.562$

b)

the higher heating values $(HHV)_f$ per unit mass of LPG = 49.9876 MJ/kg

the lower heating values $(LHV)_f$ per unit mass of LPG = 46.4933 MJ/kg

Explanation:

a)

The stoichiometric equation can be expressed as :

$0.7C_3H_8 \ + \ 0.05C_4H_{10} \ + \ 0.25 C_3H_6 \ + \ x(O_2 \ + \ 3.76N_2) ---> aCO_2 \ + \ bH_2O \ + \ cN_2$

Now, equating the coefficient of carbon; we have:

(0.7×3)+(0.05×4)+(0.25×3) = a

a = 3.05

Also, Equating the coefficient of hydrogen : we have:

(0.7 × 8) +(0.05 × 10) + ( 0.25 × 6) = 2 b

2b = 7.6

b = 3.8

Equating the coefficient of oxygen

2x = 2a + b

$x = \frac{2a+b}{2} \\ \\ x = \frac{2(3.05)+3.8}{2} \\ \\ x = 4.95$

Equating the coefficient of Nitrogen

$c = 3.76x \\ \\ c = 3.76 *4.95 \\ \\ c = 18.612$

Therefore, The overall balanced combustion reaction can now be written as :

$0.7C_3H_8 \ + \ 0.05C_4H_{10} \ + \ 0.25 C_3H_6 \ + \ x(O_2 \ + \ 3.76N_2) ---> 3.05CO_2 \ + \ 3.8H_2O \ + \ 18.612N_2$

Now; To determine the stoichiometric F/A and A/F ratios; we have:

$(F/A)_{stoichiometric} = \frac{n_f}{n_a } \\ \\ (F/A)_{stoichiometric} = \frac{1}{4.95*(1+3.76)} \\ \\ (F/A)_{stoichiometric} = 0.0424$

$(A/F)_{stoichiometric} = \frac{n_a}{n_f } \\ \\ (A/F)_{stoichiometric} = \frac{4.95*(1+3.76)}{1} \\ \\ (A/F)_{stoichiometric} = 23.562$

b)

What are the higher and lower heating values per unit mass of LPG?

Let calculate the molecular mass of the fuel in order to determine their mass fraction of the fuel components.

Molecular mass of the fuel $M_f = (0.7*M_{C_3H_5} ) + (0.05 *M_{C_4H_{10}}) + (0.25*M _{C_3H_6})$

= 30.8 + 2.9 + 10.5

= 44.2 kg/mol

Mass fraction of the fuel components can now be calculated as :

$m_{C_3H_8} = \frac{30.8}{44.2} \\ \\ m_{C_3H_8} = 0.7 \\ \\ \\ m_{C_4H_{10}} = \frac[2.9}{44.2} \\ \\ m_{C_4H_{10}} = 0.06 \\ \\ \\ m_{C_3H_6} = \frac{10.5}{44.2} \\ \\ m_{C_3H_6} = 0.24$

Finally; calculating the higher heating values $(HHV)_f$ per unit mass of LPG; we have:

$(HHV)_f=(0.7 * HHV_{C_3H_8}) + (0.06 *HHV_{C_4H_{10}})+(0.24*HHV_{C_3H_6} \\ \\ (HHV)_f=(0.7*50.38)+(0.06*49.56)+(0.24*48.95) \\ \\ (HHV)_f=49.9876 \ MJ/kg$

calculating the lower heating values $(LHV)_f$ per unit mass of LPG; we have:

$(LHV)_f = (HHV)_f - \delta H_w \\ \\ (LHV)_f = (HHV)_f - [\frac{m_w}{m_f}h_{vap}] \\ \\ (LHV)_f = 49.9876 \ MJ/kg - [\frac{3.8*18}{44.2}*2.258 \ MJ/kg] \\ \\ (LHV)_f = 46.4933 \ M/kg$

7 0

4 years ago