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Rainbow [258]
3 years ago
11

Which region in the IR spectrum could be used to distinguish between butanoic acid and 2-butanone?

Chemistry
1 answer:
Tems11 [23]3 years ago
4 0

Answer:2500-3300cm^{-1}

Explanation:We can distinguish between 2-butanone and butanoic acid by analyzing the spectra .                                          

The structure of the two compounds are slightly different as butanoic acid has an OH group whereas for 2-butanone there is no OH group present.

Please refer the attachments for structure of compounds.

Both the compounds will show carbonyl stretching frequency at around 1700-1750cm^{-1}[/tex] due to the presence of carbonyl group in both the compounds.

A broad intense peak at around 3000cm^{-1} will be observed only for butanoic acid due to the presence of OH group and 2-butanone would not show any broad intense peak at around 3000cm^{-1}.

So by analyzing the IR spectra and identifying the intense broad peak of OH we can easily distinguish between butanoic acid and 2-butanone.

Due to hydrogen bonding in between two carboxylic acid molecules ,peak broadening for OH group in butanoic acid takes place.

Generally the ketones show IR stretching in around 1700-1730cm^{-1}[/tex] due to the presence of carbonyl group.

Generally carboxylic acids show IR stretching  for carbonyl group at around 1700-1760cm^{-1}[/tex] and a broad intense peak for OH at around 2500-3000cm^{-1}[/tex].

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How many of the following are found in 15.0 kmol of xylene (C8H10)? (a) kg C8H10; (b) mol C8H10; (c) lb-mole C8H10; (d) mol (g-a
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Answer:

a) 1592.4 kg C8H10

b) 15*10³ mol C8H10

c) 33.1 lb-mole

d) 1.2 *10^5 mol C

e)  1.5 * 10^5 mol H

f)  1.44 * 10^6 grams C

g) 1.52 * 10^5 grams H

h) 9.03*10^27 molecules C8H10

Explanation:

Step 1: Data given

Number of moles C8H10 = 15.0 kmol =15000 moles

Molar mass of C8H10 = 106.16 g/mol

Step 2: Calculate mass C8H10

Mass C8H10 = moles C8H10 * molar mass C8H10

Mass C8H10 = 15000 * 106.16 g/mol

Mass C8H10 = 1592400 grams = 1592.4 kg

Step 3: Calculate moles C8H10

15.0 kmol = 15*10³ mol C8H10

Step 4: Calculate lb-mol

15.0 kmol = 33.1 lb-mole

Step 5: Calculate moles of C

For 1 mol C8H10 we have 8 moles of C

For 15*10³ mol C8H10 we have 8* 15*10³  =1.2 *10^5 mol C

Step 6: Calculate moles H

For 1 mol C8H10 we have 10 moles of H

For 15*10³ mol C8H10 we have 10* 15*10³  = 1.5 * 10^5 mol H

Step 7: Calculate mass of C

Mass C = moles C * molar mass C

Mass C = 1.2 *10^5 mol C * 12 g/mol

Mass C = 1.44 * 10^6 grams

Step 8: Calculate mass of H

Mass H = moles H * molar mass H

Mass H = 1.5 *10^5 mol H * 1.01 g/mol

Mass C = 1.52 * 10^5 grams

Step 9: Calculate molecules of C8H10

Number of molecules = number of moles * number of Avogadro

Number of molecules =  15*10³ mol C8H10 * 6.022*10^23

Number of molecules = 9.03*10^27 molecules

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