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alekssr [168]
3 years ago
6

Calculate ΔrG∘ at 298 K for the following reactions.CO(g)+H2O(g)→H2(g)+CO2(g)2-Predict the effect on ΔrG∘ of lowering the temper

ature for the reaction above.ΔrG∘ will decrease with decreasing temperature.ΔrG∘ will increase with decreasing temperature.ΔrG∘ will change slightly with decreasing temperature.
Chemistry
1 answer:
KonstantinChe [14]3 years ago
6 0

Answer:

1) ΔG°r(298 K) = - 28.619 KJ/mol

2) ΔG°r will decrease with decreasing temperature

Explanation:

  • CO(g) + H2O(g) → H2(g) + CO2(g)

1) ΔG°r = ∑νiΔG°f,i

⇒ ΔG°r(298 K) = ΔG°CO2(g) + ΔG°H2(g) - ΔG°H2O(g) - ΔG°CO(g)

from literature, T = 298 K:

∴ ΔG°CO2(g) = - 394.359 KJ/mol

∴ ΔG°CO(g) = - 137.152 KJ/mol

∴ ΔG°H2(g) = 0 KJ/mol........pure substance

∴ ΔG°H2O(g) = - 228.588 KJ/mol

⇒ ΔG°r(298 K) = - 394.359 KJ/mol + 0 KJ/mol - ( - 228.588 KJ/mol ) - ( - 137.152 KJ7mol )

⇒ ΔG°r(298 K) = - 28.619 KJ/mol

2) K = e∧(-ΔG°/RT)

∴ R = 8.314 E-3 KJ/K.mol

∴ T = 298 K

⇒ K = e∧(-28.619/(8.314 E-3)(298) = 9.624 E-6

⇒ ΔG°r = - RTLnK

If T (↓) ⇒ ΔG°r (↓)

assuming T = 200 K

⇒ ΔG°r(200 K) = - (8.314 E-3)(200)Ln(9.624E-3)

⇒ ΔG°r (200K) = - 19.207 KJ/mol < ΔG°r(298 K) = - 28.619 KJ/mol

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Answer:

Explanation:

Given parameters:

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Unknown:

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In order to find the unknown, we use some simple expressions which best explains the pH scale and the equilibrium systems of aqueous solutions.

         pH = -log₁₀[H₃O⁺]

         [H₃O⁺] = inverse log₁₀ (-pH) = 10^{-pH} = 10^{-3.5}

          [H₃O⁺] = 3.2 x 10⁻⁴moldm⁻³

       

For the  [OH⁻]:

       we use : pOH = -log₁₀ [OH⁻]

     Recall: pOH + pH = 14

                  pOH = 14 - pH = 14 - 3.5 = 10.5

  Now we plug the value of pOH into pOH = -log₁₀ [OH⁻]

                                   [OH⁻] = 10^{-pOH}

                        [OH⁻] = 10^{-10.5} = 3.2 x 10⁻¹¹moldm⁻³

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8 0
3 years ago
What pressure, in atm, would be exerted by 0.023 grams of oxygen (O2) if it occupies 31.6 mL at 91
Vikentia [17]

Answer:  A pressure of 0.681 atm would be exerted by 0.023 grams of oxygen (O_2) if it occupies 31.6 mL at 91^{o}C.

Explanation:

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1 mL = 0.001 L\\31.6 mL = 31.6 mL \times \frac{0.001 L}{1 mL}\\= 0.0316 L

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As molar mass of O_2 is 32 g/mol. Hence, the number of moles of O_2 are calculated as follows.

No. of moles = \frac{mass}{molar mass}\\= \frac{0.023 g}{32 g/mol}\\= 0.00072 mol

Using the ideal gas equation calculate the pressure exerted by given gas as follows.

PV = nRT

where,

P = pressure

V = volume

n = number of moles

R = gas constant = 0.0821 L atm/mol K

T = temperature

Substitute the value into above formula as follows.

PV = nRT\\P  \times 0.0316 L = 0.00072 mol \times 0.0821 L atm/mol K \times 364 K\\P = \frac{0.00072 mol \times 0.0821 L atm/mol K \times 364 K}{0.0316 L}\\= 0.681 atm

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4 0
2 years ago
How many moles are equal to 3.0x10^23 atoms of germanium? PLS ANSWER WITH WORK!
horrorfan [7]
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Hope this helped
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2 years ago
Which of these Group 14 elements has the most metallic properties? 1. C 2. Ge 3. Si 4. Sn
seraphim [82]
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5 0
3 years ago
Read 2 more answers
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RSB [31]
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H has 1 proton
He has 2 protons
Li has 3 protons
Be has 4 protons and so on

Each proton has a charge of +1. The other particle present in the nucleus - the neutron - has zero electrical charge and thus irrelevant when computing the charge of a nucleus. It is easy to deduce that the nucleus charge equals the number of protons (which in turn equals the atomic number). So the nucleus charges are:
for H it's+1
for He it's +2
for Li it's +3
for Be it's +4 and so on

Atom is an electroneutral particle by definition. It means it's summed charge must be 0. Since we've looked at everything within the nucleus (the protons and the neutrons) it's time we turn our gaze to the space around it, which is full of orbiting electrons. Each electron has a charge of -1. To make up for the positive charge in the nucleus you have to fill the space aroung the nucleus with negative electrons.Thanks to the elementary nature of both proton and electron charge, you simply have to take the same number of electrons as that of protons! Like this:
H has 1 proton and 1 electron
He has 2 protons and 2 electrons
Li has 3 protons and 3 electrons
Be has 4 protons and 4 electrons and so on

Fe has atomic number 26. It means that Fe has 26 protons and 26 electrons. If it's a neutral atom

You typed 3. Is it accidental? If so, then the answer is above. If not, then you could be trying to type 56Fe +3, which means an ionic iron with charge +3. Charges are formed when you have too many or too few electrons to counter-balance the prositive charge of the nucleus. Charge +3 means you're 3 electrons short to negate the nucleus positive charge.

In other words, Fe+3 has 26 protons and 23 electrons.


7 0
3 years ago
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