Answer:
16.06 L was the initial volume of the balloon.
Explanation:
Initial moles of freon in ballon = 
Initial volume of freon gas in ballon = 
Moles of freon gas added in the balloon = n = 3.50 mole
Final moles of freon in ballon = 
Final volume of freon gas in ballon = 
Using Avogadro's law:
( at constant pressure and temperature)

16.06 L was the initial volume of the balloon.
Answer:
A physical property is any property that is measurable, whose value describes a state of a physical system.
Explanation:
-color
-density
-volume
The answer to your question is false, boiling happens below the surface of a substance.