The s orbitals are not symmetrical in shape is a FALSE statement.
An s orbital is so symmetric, more specifically spherically symmetric that it looks the same from all directions.
- The atomic orbitals in the atoms of elements differ in shape.
In essence, the electrons they describe have varying probability distributions around the nucleus. The spherical symmetry of s orbitals is evident in the fact that all orbitals of a given shell in the hydrogen atom have the same energy.
- All s orbitals are spherically symmetrical. Put simply, an electron that occupies an s orbital can be found with the same probability at any orientation (at a distance) from the nucleus.
The s orbitals are therefore represented by a spherical boundary surface which is a surface which captures a high proportion of the electron density.
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Reaction of option c produces precipitate.
Rhodium on reacting with potassium phosphate produces rhodium phosphate which remain in solution due to low lattice energy for rhodium phosphate.
Niobium on reacting with lithium carbonate produces niobium carbonate and it will remain in aqueous form.
Cobalt on reacting with zinc nitrate produces cobalt nitrate. This, Co(NO3 )2 is insoluble precipitate and settles at bottom whereas zinc ion will remain in solution as follows:

Potassium ion on reacting with sodium sulfide produces potassium sulfide which remain in solution
Iodine 131 and iodine 126 are the same in the sense that, they both have the same number of electrons and protons in their atoms, it is only the number of their neutrons that is different. Iodine 131 has 78 neutrons while iodine 126 has 73 neutrons.