What is the volume of the sample at stp?

Ketones undergo a reduction when treated with sodium borohydride, NaBH4. The product of the above reaction has the following spe

Anna71 [15]

Answer:

The product is cyclohexanol

Explanation:

Firstly,

A ketone undergo a borohydride reduction reaction to form an alcohol as below,

R-CO-R' ⇒ R-CO(OH)-R'

IR Spectrum confirms that alcohol group is existed with the peak at 3400 cm⁻¹
From 1H-NMR, the product has 10 hydrogen atoms, the MS suggest that the formula is C₅H₁₀O (M = 86). With this formula, the alcohol is monosaturated. Since, the substance already underwent reduction reaction, the only way to suggest a monosaturated compound is a cyclic alcohol. So the compound is cyclopentanol.
Check with other spectroscopic properties,

3 signals of 13C NMR confirms the structure is symmetrical, δ 24.2, (-CH₂-CH₂-CH(CH₂-)-OH), δ 35.5 (-CH₂-CH₂-CH(CH₂-)-OH), δ 73.3 (-CH₂-CH₂-CH(CH₂-)-OH).

1H NMR confirms,

1.56 δ (4H, triplet) - (-CH₂-CH₂-CH-OH) ; triplet as coupling with 2 H,

1.78 δ (4H, multiplet) - (-CH₂-CH₂-CH-OH); multiplet as coupling with 2H of CH₂, 1 H of CH

3.24 δ (1H, quintet); - (-CH₂-CH₂-CH(CH₂-)-OH), coupling with4 H of 2 group of CH₂

3.58 δ (1H, singlet); - (-CH₂-CH₂-CH(CH₂-)-OH), hydrogen of alcohol group, not tend to coupling with other hydrogen

4 0

3 years ago

Calculate the solubility of hydrogen in water at an atmospheric pressure of 0.380 atm (a typical value at high altitude).

Pani-rosa [81]

The question is incomplete, here is the complete question:

Calculate the solubility of hydrogen in water at an atmospheric pressure of 0.380 atm (a typical value at high altitude).

Atmospheric Gas Mole Fraction kH mol/(L*atm)

$N_2$ $7.81\times 10^{-1}$ $6.70\times 10^{-4}$

$O_2$ $2.10\times 10^{-1}$ $1.30\times 10^{-3}$

Ar $9.34\times 10^{-3}$ $1.40\times 10^{-3}$

$CO_2$ $3.33\times 10^{-4}$ $3.50\times 10^{-2}$

$CH_4$ $2.00\times 10^{-6}$ $1.40\times 10^{-3}$

$H_2$ $5.00\times 10^{-7}$ $7.80\times 10^{-4}$

Answer: The solubility of hydrogen gas in water at given atmospheric pressure is $1.48\times 10^{-10}M$

Explanation:

To calculate the partial pressure of hydrogen gas, we use the equation given by Raoult's law, which is:

$p_{\text{hydrogen gas}}=p_T\times \chi_{\text{hydrogen gas}}$

where,

$p_A$ = partial pressure of hydrogen gas = ?

$p_T$ = total pressure = 0.380 atm

$\chi_A$ = mole fraction of hydrogen gas = $5.00\times 10^{-7}$

Putting values in above equation, we get:

$p_{\text{hydrogen gas}}=0.380\times 5.00\times 10^{-7}\\\\p_{\text{hydrogen gas}}=1.9\times 10^{-7}atm$

To calculate the molar solubility, we use the equation given by Henry's law, which is:

$C_{H_2}=K_H\times p_{H_2}$

where,

$K_H$ = Henry's constant = $7.80\times 10^{-4}mol/L.atm$

$p_{H_2}$ = partial pressure of hydrogen gas = $1.9\times 10^{-7}atm$

Putting values in above equation, we get:

$C_{H_2}=7.80\times 10^{-4}mol/L.atm\times 1.9\times 10^{-7}atm\\\\C_{CO_2}=1.48\times 10^{-10}M$

Hence, the solubility of hydrogen gas in water at given atmospheric pressure is $1.48\times 10^{-10}M$

4 0

3 years ago

The reactivity of metals on the periodic table

kari74 [83]

Explanation:

The most reactive metals are found on the left of the periodic table, in the blue column, known as the alkali metals. Their reactivity increases as we go down column (group) one. Reactive metals, when attached to less reactive metals, have the ability to prevent the less reactive metal from rusting.

8 0

3 years ago

You have 1.0 mole of each compound below. which has the greatest mass?

kramer

(a) Iron (iii) sulphate:
From the periodic table:
mass of iron = 55.845 grams
mass of sulphur = 32.065 grams
mass of oxygen = 16 grams
Iron (iii) sulphate has the formula: Fe2(SO4)3
molar mass = 2(55.845) + 3(32.065) + 3(4)(16) = 399.885 grams

(b) Sodium hydroxide:
From the periodic table:
mass of sodium = 22.989 grams
mass of oxygen = 16 grams
mass of hydrogen = 1 gram
Sodium hydroxide has the formula: NaOH
molar mass = 22.989 + 16 + 1 = 39.989 grams

(c) Barium carbonate
From the periodic table:
mass of barium = 137.327 grams
mass of carbon = 12 grams
mass of oxygen = 16 grams
Barium carbonate has the formula: BaCO3
molar mass = 137.327 + 12 + 3(16) = 197.327 grams

(d) ammonium nitrate:
From the periodic table:
mass of nitrogen = 14 grams
mass of hydrogen = 1 gram
mass of oxygen = 16 grams
Ammonium nitrate has the formula: NH4NO3
molar mass = 14 + 4(1) + 14 + 3(16) = 80 grams

(e) Lead (iv) oxide
From the periodic table:
mass of lead = 207.2 grams
mass of oxygen = 16 grams
Lead (iv) oxide has the formula: PbO2
molar mass = 207.2 + 2(16) = 239.2 grams

From the above calculations, we can see that:
Iron (iii) sulphate has the greatest mass.

5 0

4 years ago

Which electrolyte is stronger, NaOH or Ca(OH)2? Why?

nataly862011 [7]

Answer:

NaOH

Explanation:

Look at charge Na has +1 charge and Ca has +2 charge after dissociation . Greater charge Stronger lattice. And as we need weak Lattice, so NaoH is stronger base than Ca(OH)2.

8 0

3 years ago