The correct answers are :
Changing the volume of the system.
Changing the temperature of the system.
Equilibrium will remain unaffected if the concentration of products and reactants are kept the same, and the temperature of the system is kept constant.
As the system is closed, we cannot add or remove products or reactants.
Change in temperature will shift the chemical equilibrium towards the reactant or product depending on whether the reaction is exothermic or endothermic.
Also change in volume will shift the chemical equilibrium of a chemical reaction if the reactants or products or both are gases.
We assume that we have Ka= 4.2x10^-13 (missing in the question)
and when we have this equation:
H2PO4 (-) → H+ + HPO4-
and form the Ka equation we can get [H+]:
Ka= [H+] [HPO4-] / [H2PO4] and we have Ka= 4.2x10^-13 & [H2PO4-] = 0.55m
by substitution:
4.2x10^-13 = (z)(z)/ 0.55
z^2 = 2.31x 10^-13
z= 4.81x10^-7
∴[H+] = 4.81x10^-7
when PH equation is:
PH= -㏒[H+]
= -㏒(4.81x10^-7) = 6.32
Density= mass/volume. volume= 12 x 6 x 10. 415/720=.57g/cm^3
