If excess carbon disulfide reacts with 450 mL of oxygen, 150 mL of carbon dioxide and 300 mL of sulfur dioxide gases would be produced respectively.
<h3>Stoichiometric calculation</h3>
The reaction between liquid carbon disulfide and oxygen is represented by the equations below:
The mole ratio of oxygen to carbon dioxide and sulfur dioxide produced is 3:1:2.
Thus, for 450 mL oxygen, 1/3 x 450 = 150 mL of carbon dioxide will be required.
Also for 450 mL of oxygen, 2/3 x 450 = 300 mL of sulfur dioxide will be required.
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X will be hydronium (H3O)
Answer:
v = 2,66x10⁻⁵ P[H₂C₂O₄]
Explanation:
For the reaction:
H₂C₂O₄(g) → CO₂(g) + HCOOH(g)
At t = 0, the initial pressure is just of H₂C₂O₄(g). At t= 20000 s, pressures will be:
H₂C₂O₄(g) = P₀ - x
CO₂(g) = x
HCOOH(g) = x
P at t=20000 is:
P₀ - x + x + x = P₀+x. That means P at t=20000s - P₀ = x
For 1st point:
x = 92,8-65,8 = 27
Pressure of H₂C₂O₄(g) at t=20000s: 65,8-27 = 38,8
2nd point:
x = 130-92,1 = 37,9
H₂C₂O₄(g): 92,1 - 37,9 = 54,2
3rd point:
x = 157-111 = 46
H₂C₂O₄(g): 111-46 = 65
Now, as the rate law is :
v = k P[H₂C₂O₄]
Based on integrated rate law, k is:
(- ln P[H₂C₂O₄] + ln P[H₂C₂O₄]₀) / t = k
1st point:
k = 2,64x10⁻⁵
2nd point:
k = 2,65x10⁻⁵
3rd point:
k = 2,68x10⁻⁵
The averrage of this values is:
k = 2,66x10⁻⁵
That means law is:
v = 2,66x10⁻⁵ P[H₂C₂O₄]
I hope it helps!
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