1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
vesna_86 [32]
3 years ago
6

Copper(I) ions in aqueous solution react with NH 3 ( aq ) according to Cu + ( aq ) + 2 NH 3 ( aq ) ⟶ Cu ( NH 3 ) + 2 ( aq ) K f

= 6.3 × 10 10 Calculate the solubility (in g·L−1) of CuBr ( s ) ( K sp = 6.3 × 10 − 9 ) in 0.76 M NH 3 ( aq ) .
Chemistry
1 answer:
Kruka [31]3 years ago
4 0

Answer:

53.18 gL⁻¹

Explanation:

Given that:

Cu^{2+}_{(aq)} + 2NH_{3(aq)} ------>  [Cu(NH_3)_2]^+_{(aq)}      ------equation (1)

where;

Formation Constant  (k_f) = 6.3*10^{10}

However, the Dissociation of CuBr_{(s) yields:

CuBr_{(s)}      ⇄    Cu^{+}_{(aq)}  + Br^-_{(aq)}      -------------- equation (2)

where;

the Solubility Constant (k_{sp})  = 6.3 *10^{-9

From equation (1);

(k_f) = \frac{[[Cu(NH_3)_2]^+]}{[Cu^{2+}][NH_3]^{2}}            ---------  equation (3)

From equation (2)

(k_{sp})  = [Cu^+][Br^-]           ---------  equation (4)

In NH_3, the net reaction for CuBr_{(s) can be illustrated as:

CuBr_{(s)   + 2NH_{3(aq)}  ⇄  [Cu(NH_3)_2]^+_{(aq)}  + Br^-_{(aq)}

The equilibrium constant (K) can be written as :

K=\frac{[[Cu(NH_3)_2]^+][Br^-]}{[NH_3]^2}

If we multiply both the numerator and the denominator with  [Cu^+] ; we have:

K=\frac{[[Cu(NH_3)_2]^+][Br^-]}{[NH_3]^2}*\frac{[Cu^+]}{[Cu^+]}

K=\frac{[[Cu(NH_3)_2]^+}{[NH_3]^2[Cu^+]}*{[Cu^+][Br^-]}

K = k_f *k_{sp}

K= (6.3*10^{10})*(6.3*10^{-9})

K= 3.97*10^2

K ≅ 4.0*10^2

Now; we can re-write our equilibrium constant again as:

K=\frac{[[Cu(NH_3)_2]^+][Br^-]}{[NH_3]^2}

4.0*10^2 = \frac{(x)(x)}{(0.76-2x)^2}

4.0*10^2 = \frac{(x)^2}{(0.76-2x)^2}

4.0*10^2 = (\frac{(x)}{(0.76-2x)})^2

By finding the square of both sides, we have

\sqrt {4.0*10^2} = \sqrt {(\frac{(x)}{(0.76-2x)})^2

2.0*10 = \frac{x}{(0.76-2x)}

20(0.76-2x) =x

15.2 -40x=x

15.2 = 40x +x

15.2 = 41x

x = \frac{15.2}{41}

x = 0.3707 M

In gL⁻¹; the solubility of CuBr_{(s) in 0.76 M NH_3 solution will be:

= \frac{0.3707 mole of CuBr}{1L}*\frac{143.45 g}{mole of CuBr}

=  53.18 gL⁻¹

You might be interested in
HELPPPPP PLEASSEEEEE
timurjin [86]

Answer:

  • Dalton was first with the modeling
  • They soon followed so the answer is D: rutherford and bohr modeled their experiments
4 0
3 years ago
What is the percent yield of the purification system
Jlenok [28]

Answer: 90.3

Explanation:

3 0
3 years ago
why do you think you can find silver and gold on their own in rocks but calcium and magnesium are combined with other elements t
katrin [286]

Explanation:

Silver and Gold belong to a special group of metals known as the native metals. They are found naturally on their own and not in combined form in rocks.

  • These metals are found uncombined because they are unreactive.
  • They prefer to alloy with themselves.
  • Calcium and magnesium on the other hand are reactive metals.
  • The unreactivity of these metals makes them uncombined in nature.
4 0
3 years ago
Read 2 more answers
Differentiate between the three types of simple permanent tissues on the basis of their cell walls​
True [87]

Answer:

Parenchyma is the most simple and specialized tissue which is concerned mainly with the vegetative activities of the plant. The cells are isodiametric with well-developed intercellular spaces, vacuolated cytoplasm and cellulosic cell wall.

Collenchyma is the tissue of the primary body. The cells of the tissue contain protoplasm and are living without intercellular spaces. The cell wall articulate at the corners and are made up of cellulose, hemicellulose, and pectin.

Sclerenchyma is the thick-walled cell tissue. In the beginning, the cell is living and have protoplasm, but due to deposition of impermeable secondary board lignin, they become dead thick and hard.

5 0
3 years ago
Maya prepared 0.50 liters of a solution by dissolving 2.0 moles of an unknown compound in water. What is the molarity of the sol
Elena-2011 [213]

Answer:

4 M

Explanation:

Molarity can be represented by the following ratio:

Molarity = moles / volume (L)

Since you have been given both the mass and volume, you can plug the values into the equation and solve for molarity.

Molarity = moles / volumes

Molarity = 2.0 moles / 0.50 L

Molarity = 4 M

6 0
2 years ago
Other questions:
  • According to Dalton's atomic theory, which statement is true about atoms of the same element? They can be destroyed. They have i
    8·2 answers
  • How do you find a neutron number?
    9·1 answer
  • How to reproduce with a dolphin?<br> and how long will it take for the dolphin baby to come out?
    7·1 answer
  • Using the formula for velocity shown below, what is the average velocity of a car that traveled 100 miles south of where it bega
    6·1 answer
  • What is the correct order of processes in the accretion of planetesimals?
    12·2 answers
  • What is a solution of zinc and copper?<br>five letter word
    5·1 answer
  • The plant on the left is growing more because it has been receiving more water
    8·1 answer
  • How do I find the concentration of hydronium
    13·1 answer
  • What is the Formula for the volume of an irregular object?
    11·1 answer
  • What is the molarity of a solution that has 26 moles of nacl in 2. 7 l of water?.
    6·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!