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sergiy2304 [10]
3 years ago
12

Of the well-characterized elements of group 7A, which would exhibit the following properties? It reacts with the alkali metals (

M) to form a salt MX, where X is the halogen. Its hydrogen halide, HX, forms a weakly acidic solution. It is more reactive than the other halogens. It forms interhalogen compounds only of the form XA, where A is the unknown and X is another halogen.
a. fluorine
b. chlorine
c. bromine
d. iodine
Chemistry
1 answer:
dezoksy [38]3 years ago
8 0

Answer:

a. fluorine

Explanation:

Fluorine is the element of group 17 and period 2. The electronic configuration of the element is 1s^22s^22p^5.

Stable oxidation state = -1 of fluorine as it gains one electron to gain noble gas configuration.

With alkali metals, which have oxidation state of +1 form ionic compound of the form, MX where X is F.

Among the halogens, fluorine forms the most stable halide because of the comparable size of the hydrogen and fluorine. Thus, it is the weakest acid when compared with other hydrogen halides.

Fluorine is the most reactive in the halogen series and thus, combines with most of the elements.

Fluorine forms inter-halogen compounds of form XA only. Example - ClF.

Hence, option a is correct.

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A solution contains 0.0440 M Ca2 and 0.0940 M Ag. If solid Na3PO4 is added to this mixture, which of the phosphate species would
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C. Ca_3(PO_4)_2  will precipitate out first

the percentage of Ca^{2+}remaining =  12.86%

Explanation:

Given that:

A solution contains:

[Ca^{2+}] = 0.0440 \ M

[Ag^+] = 0.0940 \ M

From the list of options , Let find the dissociation of Ag_3PO_4

Ag_3PO_4 \to Ag^{3+} + PO_4^{3-}

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Solubility product constant Ksp of Ag_3PO_4 is 8.89 \times 10^{-17}

Thus;

Ksp = [Ag^+]^3[PO_4^{3-}]

replacing the known values in order to determine the unknown ; we have :

8.89 \times 10 ^{-17}  = (0.0940)^3[PO_4^{3-}]

\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}  = [PO_4^{3-}]

[PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}

[PO_4^{3-}] =1.07 \times 10^{-13}

The dissociation  of Ca_3(PO_4)_2

The solubility product constant of Ca_3(PO_4)_2  is 2.07 \times 10^{-32}

The dissociation of Ca_3(PO_4)_2   is :

Ca_3(PO_4)_2 \to 3Ca^{2+} + 2 PO_{4}^{3-}

Thus;

Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2

2.07 \times 10^{-33} = (0.0440)^3  [PO_4^{3-}]^2

\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}=   [PO_4^{3-}]^2

[PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}

[PO_4^{3-}]^2 = 2.43 \times 10^{-29}

[PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}

[PO_4^{3-}] =4.93 \times 10^{-15}

Thus; the phosphate anion needed for precipitation is smaller i.e 4.93 \times 10^{-15} in Ca_3(PO_4)_2 than  in  Ag_3PO_4  1.07 \times 10^{-13}

Therefore:

Ca_3(PO_4)_2  will precipitate out first

To determine the concentration of [Ca^+] when  the second cation starts to precipitate ; we have :

Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2

2.07 \times 10^{-33}  = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2

[Ca^{2+}]^3 =  \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}

[Ca^{2+}]^3 =1.808 \times 10^{-7}

[Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}

[Ca^{2+}] =0.00566

This implies that when the second  cation starts to precipitate ; the  concentration of [Ca^{2+}] in the solution is  0.00566

Therefore;

the percentage of Ca^{2+}  remaining = concentration remaining/initial concentration × 100%

the percentage of Ca^{2+} remaining = 0.00566/0.0440  × 100%

the percentage of Ca^{2+} remaining = 0.1286 × 100%

the percentage of Ca^{2+}remaining =  12.86%

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