Answer:
Explanation:
The relation between equilibrium constant and Ecell is given below .
E⁰cell = (RT / nF ) lnK , F is faraday constant T is 273 + 25 = 298 K
E⁰cell = 1.46 - 1.21 = .25 V
n = 2
Putting the values
.25 = (8.314 x 298 lnK) / (2 x 96485 )
lnK = 19.47
K = 2.85 x 10⁸
2 )
Change in free energy Δ G
Δ G ⁰ = nE⁰ F
n = 4
E⁰ = .4 + .83 = 1.23 V
Δ G ⁰= 4 x 1.23 x 96485
= 474706 J / mol
3 )
E⁰cell = (RT / nF ) lnK
n = 2
1.78 = 8.314 x 298 lnK / 2 x 96485
lnK = 138.638
K = 1.62 x 10⁶⁰
Answer:
15.4%
Explanation:
If Ka = 0.54 mM = 1.51x10⁻⁵
Then;
C₄H₈O₂ --------> C₄H₇O₂⁻ + H⁺
I 0.54x10⁻³ 0 0
E 0.54x10⁻³(1-x) 0.54x10⁻³x 0.54x10⁻³x
Recall that x is the percentage degree of dissociation
From the ICE table;
Ka = [C₄H₇O₂⁻] [ H⁺]/[C₄H₈O₂]
1.51x10⁻⁵=(0.54x10⁻³x) (0.54x10⁻³x)/ 0.54x10⁻³(1-x)
1.51x10⁻⁵ = 0.54x10⁻³x^2/1-x
1.51x10⁻⁵(1-x) = 0.54x10⁻³x^2
1.51x10⁻⁵ - 1.51x10⁻⁵x = 0.54x10⁻³x^2
Hence;
0.54x10⁻³x^2 + 1.51x10⁻⁵x - 1.51x10⁻⁵=0
x^2 + 0.028x - 0.028 = 0
Solving the quadratic equation here;
x = 0.154 or −0.182
Ignoring the negative result, x = 0.154
Hence, fraction of butanoic acid that is in the dissociated form in this solution = 15.4%
Phosphoric acid. Also known as orthophosphoric acid in or phosphoric(V) acid, is a weak acid with the chemical formula H3PO4. The pure compound is a colorless solid.
Density = mass / volume
therefore, density = 22/42 = 0.524 kg/m3
When a electron moves from higher shell to lower shell ,it releases energy because if it goes to lower shell without releasing energy then it will unable to do that so.as lower electron shells have low energy electrons
